Improvement of Emission Intensity for Near-infrared-emitting Ca14Zn6Al10O35:Mn4+ Phosphor by Oxygen-pressure Method

被引:32
作者
Hasegawa, Takuya [1 ]
Kim, Sun Woog [1 ,2 ]
Abe, Takeshi [1 ]
Kumagai, Shota [1 ]
Yamanashi, Ryota [1 ]
Seki, Kohei [1 ]
Uematsu, Kazuyoshi [1 ]
Toda, Kenji [1 ]
Sato, Mineo [3 ]
机构
[1] Niigata Univ, Grad Sch Sci & Technol, 8050 Ikarashi 2 Nocho, Niigata 9502181, Japan
[2] Sejong Univ, Dept Nanotechnol & Adv Mat Engn, 209 Neungdong Ro, Seoul 05006, South Korea
[3] Niigata Univ, Dept Chem & Chem Engn, 8050 Ikarashi 2 Nocho, Niigata 9502181, Japan
关键词
Mn4+-activated phosphor; Oxygen gas pressure synthesis; Near-infrared emission; CRYSTAL-FIELD; MN4+; PHOTOLUMINESCENCE; LUMINESCENCE; CAAL12O19;
D O I
10.1246/cl.160498
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We employed an oxygen-pressure method as a novel approach to improve the emission intensity of a Ca14Zn6Al10O35:Mn4+ phosphor. With this new approach, the Ca14Zn6Al10O35:Mn4+ phosphor exhibited near-infrared emission under excitation at 450 rim, and the emission intensity of a Caw Zn-6(Al0.97Mn0.03)(10)O-35 phosphor was effectively enhanced by approximately 143% compared with that of a Ca14Zn6(Al0.97Mn0.03)(10)O-35 phosphor synthesized by a conventional solid-state reaction method in air.
引用
收藏
页码:1096 / 1098
页数:3
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