Analytical expressions for electrochemical supercapacitor with potential dependent capacitance

被引:11
作者
Fernandez, A. P. R. [1 ]
Perigo, E. A. [2 ]
Faria, R. N. [1 ]
机构
[1] Nucl & Energy Res Inst, BR-05508000 Sao Paulo, Brazil
[2] ABB US Res Ctr, Raleigh, NC 27606 USA
关键词
Supercapacitors; Analytical expressions; Cyclic voltammetry; Potential dependent capacitance; ULTRACAPACITORS; MODELS;
D O I
10.1016/j.est.2021.103156
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Distinctly from ordinary capacitors which have a fixed capacitance, the capacitance of electrochemical supercapacitors is dependent on the applied potential. This feature introduces an additional complication to the analytical solution representing the supercapacitor circuit. Here a simplified equivalent circuit of electric double layer capacitors or electrochemical supercapacitors is proposed so that expressions evaluating the potentialdependent capacitance are derived considering short periods of charging and discharging process as in cyclic voltammetry carried out in a few minutes. Comparisons between such theoretical development and experimental cyclic voltammetry data - presenting a very good agreement - are presented and discussed.
引用
收藏
页数:11
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