Tetrakis(4-aminopyridine)diisothiocyanatonickel(II) and its clathrates with EtOH, Me2CO and DMSO:: structures, thermal stabilities and guest exchange

被引：13

作者：

Nassimbeni, LR ^{[1
]}

Kilkenny, ML ^{[1
]}

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 08期

关键词：

D O I：

10.1039/b010042k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures of the Werner complex, Ni(NCS)(2)(4-NH2-py)(4) as the apohost, 1, and its inclusion compounds with EtOH/Me2CO, 2, and DMSO, 3, have been elucidated. The dynamics of guest exchange between the clathrates have been monitored by DSC. The inclusion compounds can be formed by exposing the host to vapour of the guest, and powder XRD shows this reaction to be fully reversible.

引用

页码：1172 / 1175

页数：4

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