The first catena-trihydrogen triphosphide:: synthesis and crystal structure of [Na(NH3)5][Na(NH3)3(P3H3)]

被引：15

作者：

Korber, N ^{[1
]}

Aschenbrenner, J ^{[1
]}

机构：

[1] Univ Regensburg, Inst Anorgan Chem, D-93053 Regensburg, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 08期

关键词：

D O I：

10.1039/b101533h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of P-4 with sodium in liquid ammonia (P : Na ratio 3 : 5) yields crystalline NaNH2 and [Na(NH3)(5)][Na(NH3)(3)(P3H3)], which contains all-trans catena-P3H32- stabilised in the ion complex [Na(NH3)(3)(P3H3)](-).

引用

页码：1165 / 1166

页数：2

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