Synthesis and characterization of the nitrogen-centered trigonal prismatic clusters [W6NCl18]n-(n=1-3)

被引：17

作者：

Welch, EJ ^{[1
]}

Yu, CL ^{[1
]}

Crawford, NRM ^{[1
]}

Long, JR ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 17期

关键词：

cluster compounds; cyclic voltammetry; metal-metal bonding; nitrides; tungsten;

D O I：

10.1002/anie.200462585

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Central effects: Molecular salts, including Na[W6NCl 18],(Bu4N)[(Ph3P)2N][W 6NCl18], and (Bu4N)3[W 6NCl18]·MeCN, were prepared that contain [W 6NCl18]n- (n = 1-3) clusters (for an example, see picture of [W6NC;18]-), reminiscent of a fragment of WN. Cyclic-voltammetric studies indicate the accessibility of species possessing 24-27 {W6N}-based valence electrons. (Figure Presented). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2549 / 2553

页数：5

共 14 条

[1] Tungsten Oxychloride Compounds Containing [W6O6Cl12]n- (n=2, 3) Clusters
Hummel, Thorsten
Glaser, Jochen
Stroebele, Markus
Meyer, H-Juergen
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2013, 639 (14): : 2637 - 2642
[2] Synthesis and X-ray molecular structure of [WVI(C6H4S2-1,2)3] completing the structural characterization of the series [W(C6H4S2-1,2)3]n- (n=0, 1, 2):: Trigonal-prismatic versus octahedral coordination in tris(benzene-1,2-dithiolato) complexes
Huynh, H
Lügger, T
Hahn, FE
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2002, (11) : 3007 - 3009
[3] Synthesis and Electrochemical Behavior of Metal Carbonyl Isocyanoferrocene Compounds [M(CO)6-n(C≡NFc)n] (M=Cr, Mo, W; n=1, 2, 3)
Mahrholdt, Julia
Kovalski, Eduard
Noll, Julian
Vrcek, Valerije
Lang, Heinrich
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2022, 648 (17):
[4] Electrochemical characterization of a series of substituted Dawson type tungstophosphates α[P2W18-xMozVyO62]n- (x=y+z;n=6+y)
Tommasino, JB
Contant, R
Michaut, JP
Roncin, J
POLYHEDRON, 1998, 17 (2-3) : 357 - 366
[5] Metal Segregation in Bimetallic Co-Pd Carbide Carbonyl Clusters: Synthesis, Structure, Reactivity and Electrochemistry of [H6-nCo20Pd16C4(CO)48]n- (n=3-6)
Ciabatti, Iacopo
de Biani, Fabrizia Fabrizi
Femoni, Cristina
Iapalucci, Maria Carmela
Longoni, Giuliano
Zacchini, Stefano
CHEMPLUSCHEM, 2013, 78 (12): : 1456 - 1465
[6] Synthesis and crystal structures of [W(3,6-dichloro-1,2-benzenedithiolate)3]n=1, 2) and [Mo(3,6-dichloro-1,2-benzenedithiolate)3]2- :: Dependence of the coordination geometry on the oxidation number and counter-cation in trigonal-prismatic and octahedral structures
Sugimoto, H
Furukawa, Y
Tarumizu, M
Miyake, H
Tanaka, K
Tsukube, H
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (15) : 3088 - 3092
[7] Icosahedral Ga-Centred Nickel Carbonyl Clusters: Synthesis and Characterization of [H3-nNi12 (μ12-Ga)(CO)22]n- (n=2, 3) and [Ni14.3(μ12-Ga)(CO)24.3]3- Anions
Femoni, Cristina
Iapalucci, Maria Carmela
Longoni, Giuliano
Zacchini, Stefano
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (07) : 1056 - 1062
[8] Synthesis, Characterization, and Lewis Acid Behavior of [W(NC6F5)F4]xand Computational Study of W(NR)F4 (R = H, F, CH3 , CF3, C6H 5, C6 F5), W(NC6F5)F4(NCCH3), and W(NC6F5)F4(NC5H5)n(n=1, 2)
Turnbull, Douglas
Wetmore, Stacey D.
Gerken, Michael
INORGANIC CHEMISTRY, 2019, 58 (09) : 6363 - 6375
[9] Synthesis, characterization, electrochemical properties and antibacterial activity of some transition metal complexes with 2-[N-(2′-hydroxy-1′-naphthylidene)amino]-3-carboxyethyl-4,5-dimethylthiophene
Daniel, Varughese P.
Pillai, T. Prasanna Chandran
Kumari, B. Sindhu
Joseyphus, R. Selwin
Mohanan, K.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2011, 88 (11) : 1639 - 1646
[10] METAL-COMPLEXES OF PHENYLENEBISTRIAZENIDES - SYNTHESIS AND CRYSTAL-STRUCTURES OF [CP(CO)(2)M](2)(1,2-PHN(3)C(6)H(4)N(3)PH) (M=MO, W)
HORNER, M
GALVAN, JM
BECK, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (10): : 1755 - 1760

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