Effect of Yb3+ on the upconversion luminescence of Tm3+/Yb3+ co-doped La2O3-TiO2-ZrO2 glasses

被引：14

作者：

Zhang, Minghui ^{[1
]}

Liu, Yan ^{[1
]}

Yu, Huimei ^{[2
]}

Yu, Jianding ^{[1
]}

Zheng, Xiaojie ^{[1
,3
]}

Ai, Fei ^{[1
]}

Pan, Xiuhong ^{[1
]}

Zhao, Hongyang ^{[1
]}

Tang, Meibo ^{[1
]}

Wen, Haiqin ^{[1
]}

Gai, Lijun ^{[1
]}

Mao, ZhaoZhao ^{[1
]}

Wang, Chaoyue ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Ceram, Anal & Testing Ctr Inorgan Mat, Shanghai 200050, Peoples R China

[3] Shanghai Univ, Inst Low Dimens Carbons & Device Phys, Dept Phys, Shanghai 200444, Peoples R China

来源：

OPTICAL MATERIALS EXPRESS | 2015年 / 5卷 / 04期

基金：

中国国家自然科学基金;

关键词：

TITANATE GLASS; OPTICAL-ABSORPTION; FLUORESCENCE; TM3+; MECHANISMS; CERAMICS; EMISSION;

D O I：

10.1364/OME.5.000676

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Containerless processing has been used to prepare Tm3+/Yb3+ co-doped La2O3-TiO2-ZrO2 (LTZ) glasses with intense blue emission. The effects of Yb3+ ions on the thermal stability and upconversion luminescence of as-prepared LTZ glasses and glass-ceramics have been studied. Yb3+ ions perform negative effect on the thermal stability of glasses. As Yb3+ increases, the emissions can be enhanced by improving energy transfer from Yb3+ to Tm3+ and reducing energy loss. A model is proposed to discuss the effects of active ions, sensitizers, and hosts on the upconversion luminescence process. Moreover, the refractive index value and Abbe number of glasses are 2.261 and 20.7, indicating excellent optical properties. (C) 2015 Optical Society of America

引用

页码：676 / 683

页数：8

共 37 条

[1] Refractive index calculation using the structural properties of La4Ti9O24 glass [J].

Arai, Yasutomo ;

Itoh, Keiji ;

Kohara, Shinji ;

Yu, Jianding .

JOURNAL OF APPLIED PHYSICS, 2008, 103 (09)

[2] Enhanced white light emission in Er/Tm/Yb/Li codoped Y2O3 nanocrystals [J].

Bai, Yunfeng ;

Wang, Yuxiao ;

Peng, Guanya ;

Zhang, Wang ;

Wang, Yueke ;

Yang, Kun ;

Zhang, Xueru ;

Song, Yinglin .

OPTICS COMMUNICATIONS, 2009, 282 (09) :1922-1924

[3] FLUORESCENCE MECHANISMS IN TM-3+ SINGLY DOPED AND TM-3+, HO-3+ DOUBLY DOPED INDIUM-BASED FLUORIDE GLASSES [J].

BRENIER, A ;

PEDRINI, C ;

MOINE, B ;

ADAM, JL ;

PLEDEL, C .

PHYSICAL REVIEW B, 1990, 41 (08) :5364-5371

[4] A three-color, solid-state, three-dimensional display [J].

Downing, E ;

Hesselink, L ;

Ralston, J ;

Macfarlane, R .

SCIENCE, 1996, 273 (5279) :1185-1189

[5] Quantitative analysis of optical power budget of bismuth oxide-based erbium-doped fiber [J].

Hayashi, Hideaki ;

Tanabe, Setsuhisa ;

Sugimoto, Naoki .

JOURNAL OF LUMINESCENCE, 2008, 128 (03) :333-340

[6] Enhanced upconversion in Ho3+-doped transparent glass ceramics containing BaYbF5 nanocrystals [J].

Jiang, Sha ;

Guo, Hai ;

Wei, Xiantao ;

Duan, Changkui ;

Yin, Min .

JOURNAL OF LUMINESCENCE, 2014, 152 :195-198

[7] Concentration effects on the upconversion luminescence in Ho3+/Yb3+ co-doped NaGdTiO4 phosphor [J].

Jiang, Yunfeng ;

Shen, Rensheng ;

Li, Xiangping ;

Zhang, Jinsu ;

Zhong, Hua ;

Tian, Yue ;

Sun, Jiashi ;

Cheng, Lihong ;

Zhong, Haiyang ;

Chen, Baojiu .

CERAMICS INTERNATIONAL, 2012, 38 (06) :5045-5051

[8] Yb3+ concentration dependence of upconversion luminescence in Y2Sn2O7:Yb3+/Er3+ nanophosphors [J].

Liao, Jinsheng ;

Nie, Liling ;

Liu, Shaohua ;

Liu, Bao ;

Wen, He-rui .

JOURNAL OF MATERIALS SCIENCE, 2014, 49 (17) :6081-6086

[9] Mechanisms of Yb3+ sensitization to Tm3+ for blue upconversion luminescence in fluorophosphate glass [J].

Liao, Meisong ;

Wen, Lei ;

Zhao, Haoyan ;

Fang, Yongzheng ;

Sun, Hongtao ;

Hu, Lili .

MATERIALS LETTERS, 2007, 61 (02) :470-472

[10] Upconversion luminescence of Y3Al5O12 (YAG):Yb3+, Tm3+ nanocrystals [J].

Liu, M. ;

Wang, S. W. ;

Zhang, J. ;

An, L. Q. ;

Chen, L. D. .

OPTICAL MATERIALS, 2007, 30 (03) :370-374

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