Up-conversion luminescence and optical temperature sensing behaviour of Yb3+/Er3+ codoped CaWO4 material

被引:90
作者
Cheng, Xuerui [1 ]
Yang, Kun [1 ]
Wang, Jiankun [1 ]
Yang, Linfu [1 ]
Cheng, Xiaoshuai [1 ]
机构
[1] Zhengzhou Univ Light Ind, Sch Phys & Elect Engn, Zhengzhou 450002, Henan, Peoples R China
关键词
Upconversion emission; Power dependence; FIR technique; Sensor sensitivity; PHOSPHATE-GLASS; NANOCRYSTALS; NANOPARTICLES; EMISSIONS; ROUTE; GREEN; GD; CA;
D O I
10.1016/j.optmat.2016.06.029
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Present article report on structural and optical properties of Er3+/Yb3+ codoped CaWO4 phosphors. Structural properties are explored using XRD and Raman technologies. The upconversion emission has been investigated with 980 nm excitation. The upconversion emission intensity is dependent on the concentrations of Yb3+ ions and reaches a maximum at 7%. Logarithmic plots of power dependencies reveal that the green and red emissions originate from a two-photon upconversion process. Based on the photon energy and the emission spectra, the possible upconversion processes and emission mechanisms are discussed. Finally, the optical temperature sensing properties has been performed using the fluorescence intensity ratio technique based on green upconversion emissions. Its temperature sensitivity is found to be above 0.0025 K-1 in the whole temperature range of 300-540 K, revealing this phosphor to be a promising optical temperature sensing material. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:449 / 453
页数:5
相关论文
共 29 条
[1]   Analytical solution of the transfer rate equations in LiNbO3:Er3+/Yb3+ [J].
Cantelar, E ;
Cussó, F .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2000, 12 (04) :521-527
[2]   Bright white upconversion luminescence in rare-earth-ion-doped Y2O3 nanocrystals [J].
Chen, G. Y. ;
Liu, Y. ;
Zhang, Y. G. ;
Somesfalean, G. ;
Zhang, Z. G. ;
Sun, Q. ;
Wang, F. P. .
APPLIED PHYSICS LETTERS, 2007, 91 (13)
[3]   Effects of pressure on the emission of CaWO4:Eu3+ phosphor [J].
Cheng, Xuerui ;
Yuan, Chaosheng ;
Su, Lei ;
Wang, Yongqiang ;
Zhu, Xiang .
OPTICAL MATERIALS, 2014, 37 :214-217
[4]   Near-infrared quantum cutting in YVO4:Yb3+ thin-films via downconversion [J].
Cheng, Xuerui ;
Su, Lei ;
Wang, Yongqiang ;
Zhu, Xiang ;
Wei, Xiantao ;
Wang, Yuyin .
OPTICAL MATERIALS, 2012, 34 (07) :1102-1106
[5]   Infrared-to-visible upconversion emission of Er3+/Yb3+-codoped SrMoO4 phosphors as wide-range temperature sensor [J].
Du, Peng ;
Luo, Laihui ;
Yu, Jae Su .
CURRENT APPLIED PHYSICS, 2015, 15 (12) :1576-1579
[6]   The simultaneous realization of high- and low-temperature thermometry in Er3+/Yb3+-codoped Y2O3 nanoparticles [J].
Du, Peng ;
Luo, Laihui ;
Yue, Qingying ;
Li, Weiping .
MATERIALS LETTERS, 2015, 143 :209-211
[7]   Synthesis of bright multicolor down and upconversion emitting Y2Te4O11:Er:Yb nanocrystals [J].
Dwivedi, Y. ;
Mishra, Kavita ;
Rai, S. B. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 572 :90-96
[8]   Stokes and anti-Stokes luminescence from Eu/Yb:BaB4O7 nanocrystals [J].
Dwivedi, Y. ;
Rai, D. K. ;
Rai, S. B. .
OPTICAL MATERIALS, 2010, 32 (09) :913-919
[9]   High-pressure structural study of the scheelite tungstates CaWO4 and SrWO4 -: art. no. 174106 [J].
Errandonea, D ;
Pellicer-Porres, J ;
Manjón, FJ ;
Segura, A ;
Ferrer-Roca, C ;
Kumar, RS ;
Tschauner, O ;
Rodríguez-Hernández, P ;
López-Solano, J ;
Radescu, S ;
Mujica, A ;
Muñoz, A ;
Aquilanti, G .
PHYSICAL REVIEW B, 2005, 72 (17)
[10]   Upconversion luminescence in BaYF5, BaGdF5 and BaLuF5 nanocrystals doped with Yb3+/Ho3+, Yb3+/Er3+ or Yb3+/Tm3+ ions [J].
Grzyb, Tomasz ;
Balabhadra, Sangeetha ;
Przybylska, Dominika ;
Weclawiak, Mariusz .
JOURNAL OF ALLOYS AND COMPOUNDS, 2015, 649 :606-616