Rare-Earth-Catalyzed C-H Silylation of Aromatic Heterocycles with Hydrosilanes

被引：17

作者：

Xu, Wenxuan ^{[1
]}

Teng, Huailong ^{[2
]}

Luo, Yong ^{[1
]}

Lou, Shaojie ^{[2
]}

Nishiura, Masayoshi ^{[1
,2
]}

Hou, Zhaomin ^{[1
,2
]}

机构：

[1] RIKEN Cluster Pioneering Res, Organmetall Chem Lab, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

[2] RIKEN Ctr Sustainable Resource Sci, Adv Catalysis Res Grp, 2-1 Hirosawa, Wako, Saitama 3510198, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2020年 / 15卷 / 06期

关键词：

Rare-earth Metals; Hydrosilylation; Heterocycles; C-H Activation; METHYL SULFIDES; BOND ADDITION; PYRIDINES; ALKYLATION; COMPLEX; ALKENES; ARENES;

D O I：

10.1002/asia.202000089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic C-H silylation of a variety of aromatic heterocycles such as furan, pyrrole and thiophene derivatives with secondary hydrosilanes has been achieved by using an yttrium metallocene complex. This protocol provides an efficient and straightforward way for the synthesis of a series of silylated heteroaromatic compounds containing tertiary silane moieties without the need for an additive or H-2 acceptor.

引用

页码：753 / 756

页数：4

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