Synthesis and structural characterization of thermally stable group 13 hydride complexes derived from a gallium(I) carbene analogue

被引：69

作者：

Baker, RJ ^{[1
]}

Jones, C ^{[1
]}

Kloth, M ^{[1
]}

Platts, JA ^{[1
]}

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 23期

关键词：

density functional calculations; group; 13; elements; hydrides; metal-metal interactions; structure elucidation;

D O I：

10.1002/anie.200351281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first covalently bonded metal complexes derived from an anionic gallium carbene analogue (see picture) show remarkable thermal stability in the solid state. This fact suggests that gallium(1) heterocycles should prove to be versatile ligands towards both main-group and transition-metal fragments.

引用

页码：2660 / 2663

页数：4

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