iron containing alumina supported catalyst;
nanotubes;
Mossbauer spectroscopy;
XPS spectroscopy;
D O I:
10.1117/12.501324
中图分类号:
TM [电工技术];
TN [电子技术、通信技术];
学科分类号:
0808 ;
0809 ;
摘要:
Characterization of iron containing alumina supported catalysts was performed by TEM, Mossbauer and XPS spectroscopy during formation of multiwall carbon nanotubes from acetylene at 1000 K TEM images showed that carbon fibers (outer diameter is around 20-40 mn) were generated on Fe/Al2O3 Samples while on the bimetallic Fe,Co/Al2O3 carbon nanotubes with an average diameter of 8-12 nm were formed. XPS spectra revealed that Fe-Co alloy formed during the interaction. of Fe,Co/Al2O3 and acetylene at 1000 K. The formation of the bimetallic alloy was proven by Mossbauer spectroscopy as well.