Selective Pure-Phase Synthesis of the Multiferroic BaMF4 (M = Mg, Mn, Co, Ni, and Zn) Family

被引：42

作者：

Kim, Sun Woo ^{[1
]}

Chang, Hong Young ^{[1
]}

Halasyamani, P. Shiv ^{[1
]}

机构：

[1] Univ Houston, Dept Chem, Houston, TX 77204 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 50期

关键词：

BOND-VALENCE PARAMETERS; CRYSTAL-STRUCTURE; FLUORIDE; BAMGF4; GROWTH;

D O I：

10.1021/ja108965s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A low temperature, high yield hydrothermal route has been discovered for the phase-pure synthesis of the multiferroic BaMF4 (M = Mg, Mn, Co, Ni, and Zn) family. The synthesis involves the use of CF3COOH instead of HF in an aqueous medium and, under the correct conditions, produces pure and polycrystalline BaMF4. In addition to the synthetic description, second-harmonic generation, thermogravimetric, and differential scanning calorimetry data are presented.

引用

页码：17684 / 17685

页数：2

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