Revised equations for determining the critical properties of NaCl-H2O system

被引:0
作者
Gong, Qingjie [1 ,2 ]
Yu, Chongwen [2 ]
Zhang, Ronghua [3 ]
Han, Dongyu [2 ]
机构
[1] China Univ Geosci, State Key Lab Geol Proc & Mineral Resources, Beijing 100083, Peoples R China
[2] China Univ Geosci, Sch Earth Sci & Resources, Beijing 100083, Peoples R China
[3] Chinese Acad Geol Sci, Inst Mineral Resources, Beijing 100037, Peoples R China
来源
PROCEEDINGS OF THE IAMG '07: GEOMATHEMATICS AND GIS ANALYSIS OF RESOURCES, ENVIRONMENT AND HAZARDS | 2007年
基金
中国国家自然科学基金;
关键词
D O I
暂无
中图分类号
P5 [地质学];
学科分类号
0709 ; 081803 ;
摘要
Revised equations for determining the critical properties of NaCl-H2O system were fitted on the previous critical data of NaCl-H2O solutions. They are T = 374e(0.02267S+0.00004277S2) , P = 221e(0.04156S+0.1 160S1/2) and V = 3.11e(-0.23594 Psi+0.002837 Psi 2) where T, P, V and S are the critical temperature, critical pressure, critical volume and the salinity of NaCl-H2O solution with the units of degrees C, bar, cm(3)/g and weight percent of NaCl respectively, and Psi=ln(S+1). These equations are valid for the salinities up to 36.6% NaCl by weight and temperatures up to 900 degrees C, which are adequate for the study on the mechanism of supercritical geofluids taking part in the hydrothermal metallic mineralization.
引用
收藏
页码:751 / +
页数:3
相关论文
共 50 条
[1]   Revised critical curve for the system H2O-NaCl [J].
Driesner, T ;
Heinrich, CA .
GEOCHIMICA ET COSMOCHIMICA ACTA, 2002, 66 (15A) :A196-A196
[2]   Metastable eutectic melting in the NaCl-H2O system [J].
Drebushchak, V. A. ;
Ogienko, A. G. ;
Yunoshev, A. S. .
THERMOCHIMICA ACTA, 2017, 647 :94-100
[3]   NEAR-CRITICAL NACL-H2O - AN EQUATION OF STATE AND DISCUSSION OF ANOMALOUS PROPERTIES [J].
PITZER, KS ;
TANGER, JC .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1988, 9 (05) :635-648
[4]   THE SYSTEM NACL-H2O AT SUPERCRITICAL TEMPERATURES AND PRESSURES [J].
COPELAND, CS ;
SILVERMAN, J ;
BENSON, SW .
JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (01) :12-16
[5]   MOLAL VOLUMES AND COMPRESSIBILITIES OF THE SYSTEM NACL-H2O ABOVE THE CRITICAL TEMPERATURE OF WATER [J].
BENSON, SW ;
COPELAND, CS ;
PEARSON, D .
JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (12) :2208-2212
[6]   SYNTHETIC FLUID INCLUSIONS .9. CRITICAL PVTX PROPERTIES OF NACL-H2O SOLUTIONS [J].
KNIGHT, CL ;
BODNAR, RJ .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1989, 53 (01) :3-8
[7]   Thermodynamic properties of supercritical NaCl-H2O system by molecular simulation and perturbation theory [J].
Duan, Liping ;
Lu, Jiufang ;
Li, Yigui .
Huagong Xuebao/Journal of Chemical Industry and Engineering (China), 2001, 52 (10) :872-876
[8]   ON THE NACL-H2O COEXISTENCE CURVE NEAR THE CRITICAL-TEMPERATURE OF H2O [J].
HARVEY, AH ;
SENGERS, JMHL .
CHEMICAL PHYSICS LETTERS, 1989, 156 (04) :415-417
[9]   Phase relations in the system MgO-NaCl-H2O:: The dehydroxylation of brucite in the presence of NaCl-H2O fluids [J].
Bai, TB ;
van Groos, AFK .
AMERICAN MINERALOGIST, 1998, 83 (3-4) :205-212
[10]   CRITICAL EXPONENTS FOR THE COEXISTENCE CURVES FOR NACL-H2O NEAR THE CRITICAL-TEMPERATURE OF H2O - REPLY [J].
PITZER, KS ;
TANGER, JC .
CHEMICAL PHYSICS LETTERS, 1989, 156 (04) :418-419