Improving Interfacial Interaction of L-Phenylalanine-Functionalized Graphene Nanofiller and Poly(vinyl alcohol) Nanocomposites for Obtaining Significant Membrane Properties: Morphology, Thermal, and Mechanical Studies

被引:29
作者
Abdolmaleki, Amir [1 ,2 ,3 ]
Mallakpour, Shadpour [1 ,2 ,3 ]
Borandeh, Sedigheh [1 ]
机构
[1] Isfahan Univ Technol, Organ Polymer Chem Res Lab, Dept Chem, Esfahan 8415683111, Iran
[2] Isfahan Univ Technol, Nanotechnol & Adv Mat Inst, Esfahan 8415683111, Iran
[3] Isfahan Univ Technol, Ctr Excellence Sensors & Green Chem, Dept Chem, Esfahan 8415683111, Iran
关键词
POLYMER NANOCOMPOSITES; OXIDE NANOCOMPOSITES; SHEETS; NANOMATERIALS; PERFORMANCE; NANOSHEETS; CHEMISTRY; STRATEGY; GREEN;
D O I
10.1002/pc.23371
中图分类号
TB33 [复合材料];
学科分类号
摘要
In polymer nanocomposite synthesis, the challenges are achieving well dispersion of nanofiller and its maximum interfacial interaction with polymer matrix at low loading percent. In this study, the preparation of poly (vinyl alcohol) (PVA) nanocomposites with L-phenylalanine-functionalized graphene (f-graphene) using a simple water solution processing method is reported. Graphene layers were functionalized with L-phenylalanine amino acid as a biocompatible and environmentally friendly modifier. The obtained PVA/f-graphene nanocomposite membranes were smooth, uniform, and flexible. Efficient interaction was found between f-graphene and PVA matrix, which caused significant improvement in mechanical and thermal properties of the graphene-based nanocomposite with homogeneous dispersion. (C) 2015 Society of Plastics Engineers
引用
收藏
页码:1924 / 1935
页数:12
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