Role of carbon quantum dots and film thickness on enhanced UV shielding capability of flexible polymer film containing carbon quantum dots/N-doped ZnO nanoparticles

被引:27
作者
Uthirakumar, Periyayya [1 ,2 ]
Devendiran, M. [2 ]
Yun, Jin-Hyeon [1 ]
Kim, Gyu Cheol [1 ]
Kalaiarasan, S. [2 ]
Lee, In-Hwan [1 ]
机构
[1] Korea Univ, Dept Mat Sci & Engn, Seoul 02841, South Korea
[2] Sona Coll Technol, Nanosci Ctr Optoelect & Energy Devices, Salem 636005, Tamil Nadu, India
基金
新加坡国家研究基金会;
关键词
Carbon quantum dots; Zinc oxide; UV-shielding; Polymer film; Nanoparticles; POLY(VINYL ALCOHOL); TIO2; NANOPARTICLES; NANOCOMPOSITE FILMS; LIGHT; TRANSPARENT; PERFORMANCE; FABRICATION; EFFICIENCY; COATINGS;
D O I
10.1016/j.optmat.2018.08.016
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report a simple method for preparing flexible polymer film containing carbon quantum dots/N-doped ZnO (CQD/N-ZnO) nanoparticles, as UV shielding material. The polymer film showed an enhanced UV shielding capability with increasing of CQD/N-ZnO nanoparticles. The maximum of 47% of UV shielding capability was achieved with 1 wt.% of CQD/N-ZnO nanoparticles and two-order enhancement was achieved by controlling film thickness to 250 mu m. It was found that CQDs plays important role to promote compatibility of hydrophilic ZnO into hydrophobic polymer matrix without disturbing the transparency of the film. An excellent UV shielding capability of 85% and 92% was witnessed in 250 mu m thick polymer film under a UV lamp and direct daylight, respectively.
引用
收藏
页码:771 / 777
页数:7
相关论文
共 34 条
  • [21] Preparation and UV-shielding property of Zr0.7Ce0.3O2-kaolinite nanocomposites
    Nallis, Kry
    Katsumata, Ken-ichi
    Isobe, Toshihiro
    Okada, Kiyoshi
    Bone, Phat
    Othman, Radzali
    [J]. APPLIED CLAY SCIENCE, 2013, 80-81 : 147 - 153
  • [22] Preparation and Characterization of Silanized TiO2 Nanoparticles and Their Application in Toner
    Ni, Weishuang
    Wu, Songping
    Ren, Qun
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (40) : 13157 - 13163
  • [23] Inorganic and organic UV filters: Their role and efficacy in sunscreens and suncare product
    Serpone, Nick
    Dondi, Daniele
    Albini, Angelo
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (03) : 794 - 802
  • [24] Effect of R-TiO2 and ZnO nanoparticles on the UV-shielding efficiency of water-borne acrylic coating
    Thien Vuong Nguyen
    Phi Hung Dao
    Khanh Linh Duong
    Quoc Hoan Duong
    Quoc Trung Vu
    Anh Hiep Nguyen
    Van Phuc Mac
    Trong Lu Le
    [J]. PROGRESS IN ORGANIC COATINGS, 2017, 110 : 114 - 121
  • [25] Transparent and flexible thin films of ZnO-polystyrene nanocomposite for UV-shielding applications
    Tu, Yao
    Zhou, Li
    Jin, Yi Zheng
    Gao, Chao
    Ye, Zhi Zhen
    Yang, Ye Feng
    Wang, Qing Ling
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (08) : 1594 - 1599
  • [26] Uthirakumar P., 2015, RSC ADV, V5, P71968
  • [27] Surfactant-free synthesis of leaf-like hierarchical CuO nanosheets as a UV light filter
    Uthirakumar, Periyayya
    Muthulingam, S.
    Khan, Rizwan
    Yun, Jin Hyeon
    Cho, Han-Su
    Lee, In-Hwan
    [J]. MATERIALS LETTERS, 2015, 156 : 191 - 194
  • [28] Organic Solvent Assisted Growth of Flower-like ZnO for Enhanced Photocatalytic Activities
    Uthirakumar, Periyayya
    Muthulingam, S.
    Ryu, Beo Deul
    Kang, Ji Hye
    Periyasamy, A.
    Prabakaran, M.
    Hong, Chang-Hee
    [J]. CURRENT NANOSCIENCE, 2013, 9 (03) : 335 - 340
  • [29] Fabrication of Fe3+ doped Mg/Al layered double hydroxides and their application in UV light-shielding coatings
    Wang, Xiaolong
    Zhou, Shuxue
    Wu, Limin
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2014, 2 (29) : 5752 - 5758
  • [30] A Novel UV-Shielding and Transparent Polymer Film: When Bioinspired Dopamine-Melanin Hollow Nanoparticles Join Polymers
    Wang, Yang
    Su, Jing
    Li, Ting
    Ma, Piming
    Bai, Huiyu
    Xie, Yi
    Chen, Mingqing
    Dong, Weifu
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (41) : 36281 - 36289