Comparative behavior of conjugates of tantalum phthalocyanines with gold nanoparticles or single walled carbon nanotubes towards bisphenol A electrocatalysis

被引:15
作者
Chauke, Vongani P. [1 ]
Antunes, Edith [1 ]
Nyokong, Tebello [1 ]
机构
[1] Rhodes Univ, Dept Chem, ZA-6140 Grahamstown, South Africa
基金
新加坡国家研究基金会;
关键词
Gold nanoparticles; Tantalum phthalocyanine; Bisphenol A; Single walled carbon nanotubes; COBALT PHTHALOCYANINE; ELECTRODE; OXIDATION; FUNCTIONALIZATION; NITRITE; FILM;
D O I
10.1016/j.jelechem.2011.06.019
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The characterization of tantalum phthalocyanine conjugates with gold nanoparticles and single wall carbon nanotubes as well as their electrocatalytic oxidation of bisphenol A is hereby presented. The formation of the conjugates was confirmed by X-ray diffraction and transmission electron microscope techniques. Single walled carbon nanotube conjugates of TaPc complexes showed the best catalysis as well as less passivation for bisphenol A detection and significant recovery of similar to 98% compared to gold nanoparticle conjugates. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 7
页数:7
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