Self-Assembled Structures of Amphiphilic Ionic Block Copolymers: Theory, Self-Consistent Field Modeling and Experiment

被引：78

作者：

Borisov, Oleg V. ^{[1
,2
]}

Zhulina, Ekaternia B. ^{[2
]}

Leermakers, Frans A. M. ^{[3
]}

Mueller, Axel H. E. ^{[4
]}

机构：

[1] UMR 5254 CNRS UPPA, Inst Pluridisciplinaire Rech Environm & Mat, Pau, France

[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia

[3] Wageningen Univ, Lab Phys Chem & Colloid Sci, NL-6703 HB Wageningen, Netherlands

[4] Univ Bayreuth, Bayreuther Zentrum Kolloide & Grenzflachen, D-95440 Bayreuth, Germany

来源：

SELF ORGANIZED NANOSTRUCTURES OF AMPHIPHILIC BLOCK COPOLYMERS I | 2011年 / 241卷

基金：

俄罗斯基础研究基金会;

关键词：

Amphiphilic block copolymers; Micelles; Polyelectrolytes; Polymorphism; Self-assembly; ACID) DIBLOCK COPOLYMERS; POLY(N-BUTYL ACRYLATE)-BLOCK-POLY(ACRYLIC ACID); SOLUBLE INTERPOLYELECTROLYTE COMPLEXES; STATISTICAL THERMODYNAMICS; ASSOCIATION COLLOIDS; POLYISOBUTYLENE-BLOCK-POLY(METHACRYLIC ACID); POLYELECTROLYTE BRUSHES; POLYMERIC MICELLES; CHARGED BLOCK; MORPHOLOGICAL TRANSITIONS;

D O I：

10.1007/12_2011_114

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

We present an overview of statistical thermodynamic theories that describe the self-assembly of amphiphilic ionic/hydrophobic diblock copolymers in dilute solution. Block copolymers with both strongly and weakly dissociating (pH-sensitive) ionic blocks are considered. We focus mostly on structural and morphological transitions that occur in self-assembled aggregates as a response to varied environmental conditions (ionic strength and pH in the solution). Analytical theory is complemented by a numerical self-consistent field approach. Theoretical predictions are compared to selected experimental data on micellization of ionic/hydrophobic diblock copolymers in aqueous solutions.

引用

页码：57 / 129

页数：73

共 140 条

[1] ADSORPTION OF CHAIN MOLECULES WITH A POLAR HEAD A-SCALING DESCRIPTION [J].

ALEXANDER, S .

JOURNAL DE PHYSIQUE, 1977, 38 (08) :983-987

[2] Thermo- and pH-responsive micelles of poly(acrylic acid)-block-poly(N,N-diethylacrylamide) [J].

André, X ;

Zhang, MF ;

Müller, AHE .

MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (07) :558-563

[3]

Andre X., 2007, POLYM MAT SCI ENG, V96, P560

[4] Temperature dependence of the colloidal stability of neutral amphiphilic polymers in water [J].

Aseyev, VO ;

Tenhu, H ;

Winnik, FM .

CONFORMATION-DEPENDENT DESIGN OF SEQUENCES IN COPOLYMERS II, 2006, 196 (1-85) :1-85

[5] Polyelectrolyte brushes [J].

Ballauff, Matthias ;

Borisov, Oleg .

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2006, 11 (06) :316-323

[6] Sphere, cylinder, and vesicle nanoaggregates in poly (styrene-b-isoprene) diblock copolymer solutions [J].

Bang, J ;

Jain, SM ;

Li, ZB ;

Lodge, TP ;

Pedersen, JS ;

Kesselman, E ;

Talmon, Y .

MACROMOLECULES, 2006, 39 (03) :1199-1208

[7] Ionizable polyelectrolyte brushes: brush height and electrosteric interaction [J].

Biesheuvel, PM .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 275 (01) :97-106

[8] SCALING THEORY OF SUPERMOLECULAR STRUCTURES IN BLOCK COPOLYMER SOLVENT SYSTEMS .1. MODEL OF MICELLAR STRUCTURES [J].

BIRSHTEIN, TM ;

ZHULINA, EB .

POLYMER, 1989, 30 (01) :170-177

[9] CONFORMATIONS OF STAR-BRANCHED MACROMOLECULES [J].

BIRSHTEIN, TM ;

ZHULINA, EB .

POLYMER, 1984, 25 (10) :1453-1461

[10] TEMPERATURE CONCENTRATION DIAGRAM FOR A SOLUTION OF STAR-BRANCHED MACROMOLECULES [J].

BIRSHTEIN, TM ;

ZHULINA, EB ;

BORISOV, OV .

POLYMER, 1986, 27 (07) :1078-1086

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