Functionalization of multi-wall carbon nanotubes with silane and its reinforcement on polypropylene composites

被引:107
作者
Zhou, Zhen [1 ]
Wang, Shifeng [1 ]
Lu, Lan [1 ]
Zhang, Yinxi [1 ]
Zhang, Yong [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
关键词
carbon nanotubes; polymers; mechanical properties; sol-gel methods;
D O I
10.1016/j.compscitech.2008.02.003
中图分类号
TB33 [复合材料];
学科分类号
摘要
Multi-wall carbon nanotubes (MWCNTs) were functionalized with a silane coupling agent. The MWCNTs were first coated with inorganic silica by a sol-gel process and then grafted with 3-methacryloxypropyltrimethoxysilane (3-MPTS). The grafting of 3-MPTS onto the MWCNTs surface was confirmed by Fourier-transform infrared spectroscopy, transmission electron microscopy and X-ray photoelectron spectra. Polypropylene (PP) composites filled with raw MWCNTs and functionalized MWCNTs were prepared and characterized. The PP/3-MPTS functionalized MWCNTs composite has higher tensile strength than the PP/raw MWCNTs composite. This is explained by the organic groups of 3-MPTS grafted onto the surface of MWCNTs. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1727 / 1733
页数:7
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