Quantum dot-polymethacrylate composites for the analysis of NOx by fluorescence spectroscopy

被引:26
作者
Fabregat, Victor [1 ]
Angeles Izquierdo, M. [1 ]
Isabel Burguete, M. [1 ]
Galindo, Francisco [1 ]
Luis, Santiago V. [1 ]
机构
[1] Univ Jaume 1, Dept Quim Inorgan & Organ, E-12071 Castellon de La Plana, Spain
关键词
Nitric oxide; Nitrogen oxides; Quantum dots; Fluorescence; Sensors; NITRIC-OXIDE; 1,2-DIAMINOANTHRAQUINONE DAQ; SENSOR; PHOTOLUMINESCENCE; PROGRESS; HEALTH; PROBES; FILMS;
D O I
10.1016/j.ica.2011.09.052
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new type of hybrid materials composed by core-shell (CdSe/ZnS) quantum dots adsorbed on polymethacrylate surfaces has been synthesized and characterized, specially by means of time-resolved fluorimetry. The ability of such materials to sense NO and NOx has been tested, with promising results. Fluorescence quenching measurements afford limits of detection of ca. 0.1 ppm for NO and of ca. 1.0 ppm for NOx, which opens the way for the development of new materials with analytical applications. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:212 / 217
页数:6
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