Axial bonding capabilities of square planar d(8)-ML(4) complexes. Theoretical study and structural correlations

被引：85

作者：

Aullon, G ^{[1
]}

Alvarez, S ^{[1
]}

机构：

[1] UNIV BARCELONA,DEPT QUIM INORGAN,E-08028 BARCELONA,SPAIN

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 11期

关键词：

D O I：

10.1021/ic951643w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A qualitative molecular orbital study and a structural analysis of the bonding capabilities of the metal atoms in square planar ML(4) complexes of d(8) ions are presented. In addition to analyzing the donor-acceptor properties of the metal atom in such complexes, the following aspects are also studied: (a) the effect of axial groups (bases or acids) on the donor-acceptor properties of the metal atom; (b) the effect of the axial groups on the deviation of the ML(4) ensemble from planarity; (c) the effect of an axial group on the bond between the metal atom and another group in trans; and (d) the implications on chemical reactivity.

引用

页码：3137 / 3144

页数：8

共 85 条

[21] OXIDATIVE INSERTION AS FRONTSIDE S(N)2 SUBSTITUTION - A THEORETICAL-STUDY OF THE MODEL REACTION SYSTEM PD+CH3CL
BICKELHAUPT, FM
ZIEGLER, T
SCHLEYER, PV
[J]. ORGANOMETALLICS, 1995, 14 (05) : 2288 - 2296
[22] AGOSTIC PD...H+...NHR2 AND APICAL PD...NHR2 INTERACTIONS - THE SYNTHESIS AND STRUCTURES OF [PD(II)CL2(H[9]ANEN3)]+, THE PD(II)-PD(II) DIMER [(H[9]ANEN3)CL2PD-PDCL2(H[9]ANEN3)]2+, AND [PD(ME3[9]ANEN3)(NCME)2]2+
BLAKE, AJ
HOLDER, AJ
ROBERTS, YV
SCHRODER, M
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) : 260 - 262
[23] SYNTHESIS AND 2D NMR-STUDIES OF (BIS(PYRAZOLYL)BORATO)RHODIUM(I) COMPLEXES WITH WEAK RH...H...C INTERACTIONS AND THE X-RAY CRYSTAL-STRUCTURE OF ((CYCLOOCTANE-1,5-DIYL)BIS(PYRAZOL-1-YL)BORATO)(1,5-CYCLOOCTADIENE)RHODIUM
BORTOLIN, M
BUCHER, UE
RUEGGER, H
VENANZI, LM
ALBINATI, A
LIANZA, F
TROFIMENKO, S
[J]. ORGANOMETALLICS, 1992, 11 (07) : 2514 - 2521
[24] HYDROGEN-BONDING BY CISPLATIN DERIVATIVES - EVIDENCE FOR THE FORMATION OF N-H ... CL AND N-H ... PT BONDS IN [NPRN4]2([PTCL4].CIS-[PTCL2(NH2ME)2])
BRAMMER, L
CHARNOCK, JM
GOGGIN, PL
GOODFELLOW, RJ
KOETZLE, TF
ORPEN, AG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (06) : 443 - 445
[25] Cattalini L., 1970, PROG INORG CHEM, V13, P263
[26] CRABTREE RH, 1988, ORGANOMETALLIC CHEM, P130
[27] AN APPRAISAL OF SQUARE-PLANAR SUBSTITUTION-REACTIONS
CROSS, RJ
[J]. ADVANCES IN INORGANIC CHEMISTRY, 1989, 34 : 219 - 292
[28] DART JW, 1978, J CHEM SOC DALTON, P2039
[29] KINETICS AND MECHANISM OF OXIDATIVE ADDITION OF METHYL-IODIDE TO 4-COORDINATE AND 5-COORDINATE IRIDIUM(I) COMPLEXES
DEWAAL, DJA
GERBER, TIA
LOUW, WJ
[J]. INORGANIC CHEMISTRY, 1982, 21 (03) : 1259 - 1260
[30] PHTHALOCYANINECOBALT(I) SALTS, SUPERNUCLEOPHILIC VITAMIN-B12 MODELS STABLE IN NEUTRAL MEDIUM
ECKERT, H
UGI, I
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1975, 14 (12) : 825 - 826

← 1 2 3 4 5 6 7 8 9 →