Axial bonding capabilities of square planar d(8)-ML(4) complexes. Theoretical study and structural correlations

被引：85

作者：

Aullon, G ^{[1
]}

Alvarez, S ^{[1
]}

机构：

[1] UNIV BARCELONA,DEPT QUIM INORGAN,E-08028 BARCELONA,SPAIN

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 11期

关键词：

D O I：

10.1021/ic951643w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A qualitative molecular orbital study and a structural analysis of the bonding capabilities of the metal atoms in square planar ML(4) complexes of d(8) ions are presented. In addition to analyzing the donor-acceptor properties of the metal atom in such complexes, the following aspects are also studied: (a) the effect of axial groups (bases or acids) on the donor-acceptor properties of the metal atom; (b) the effect of the axial groups on the deviation of the ML(4) ensemble from planarity; (c) the effect of an axial group on the bond between the metal atom and another group in trans; and (d) the implications on chemical reactivity.

引用

页码：3137 / 3144

页数：8

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