Axial bonding capabilities of square planar d(8)-ML(4) complexes. Theoretical study and structural correlations

被引：85
作者：
Aullon, G [1 ]
Alvarez, S [1 ]
机构：
[1] UNIV BARCELONA,DEPT QUIM INORGAN,E-08028 BARCELONA,SPAIN
来源：
INORGANIC CHEMISTRY | 1996年 / 35卷 / 11期
关键词：
D O I：
10.1021/ic951643w
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A qualitative molecular orbital study and a structural analysis of the bonding capabilities of the metal atoms in square planar ML(4) complexes of d(8) ions are presented. In addition to analyzing the donor-acceptor properties of the metal atom in such complexes, the following aspects are also studied: (a) the effect of axial groups (bases or acids) on the donor-acceptor properties of the metal atom; (b) the effect of the axial groups on the deviation of the ML(4) ensemble from planarity; (c) the effect of an axial group on the bond between the metal atom and another group in trans; and (d) the implications on chemical reactivity.
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页码：3137 / 3144
页数：8
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