A new catalytic approach to germasiloxanes

被引：21

作者：

Hreczycho, Grzegorz ^{[1
]}

Frackowiak, Dawid ^{[1
]}

Pawluc, Piotr ^{[1
]}

Marciniec, Bogdan ^{[1
]}

机构：

[1] Adam Mickiewicz Univ, PL-60780 Poznan, Poland

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 01期

关键词：

Silylative coupling; Silanol; Vinylgermane; Triruthenium dodecacarbonyl; TRANSITION-METAL-COMPLEXES; CARBON-HYDROGEN BONDS; O-SILYLATION; ROUTE; SILICON; VINYLSILANE; GERMANIUM; SILOXANE; ALCOHOL; OXYGEN;

D O I：

10.1016/j.tetlet.2010.10.153

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new ruthenium(0) complex catalyzed coupling reaction of silanols with vinylgermanes leading to SiO-Ge bond formation with the evolution of ethylene is described. Under optimum conditions the catalytic O-germylation of silanols gives exclusively germasiloxanes. (C) 2010 Elsevier Ltd. All rights reserved.

引用

收藏

页码：74 / 76

页数：3

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