Copper-catalyzed protodecarboxylation of aromatic carboxylic acids

被引：178

作者：

Goossen, Lukas J. ^{[1
]}

Thiel, Werner R. ^{[1
]}

Rodriguez, Nuria ^{[1
]}

Linder, Christophe ^{[1
]}

Melzer, Bettina ^{[1
]}

机构：

[1] Tech Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2007年 / 349卷 / 14-15期

关键词：

arenes; carboxylic acids; catalysis; copper; decarboxylation; DECARBOXYLATION; MECHANISMS; INITIO;

D O I：

10.1002/adsc.200700223

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A catalyst generated from copper(I) oxide and 4,7-diphenyl-1,10-phenanthroline for the first time allows the catalytic protodecarboxylation even of deactivated aromatic carboxylic acids, giving rise to the corresponding arenes. Based on DFT calculations, a reaction pathway is proposed that accurately reflects the experimental results, such as the observed reactivity order of the substrates.

引用

页码：2241 / 2246

页数：6

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