The [1,2]- and [1,4]-Wittig rearrangement

被引：13

作者：

Wang, Fan ^{[1
]}

Wang, Juhui ^{[1
]}

Zhang, Yan ^{[1
]}

Yang, Jingyue ^{[1
]}

机构：

[1] Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Hebei, Peoples R China

来源：

TETRAHEDRON | 2020年 / 76卷 / 05期

关键词：

1,4-Wittig rearrangement; 1,4]-Wittig rearrangement; Mechanism; Scope; Stereochemistry; Application; DEFINED ALPHA-ALKOXYALKYLLITHIUMS; IMINO 1,2-WITTIG REARRANGEMENT; BENZYL ETHERS INHIBITION; WITTIG REARRANGEMENT; STEREOSELECTIVE-SYNTHESIS; FORMAL SYNTHESIS; ABSOLUTE-CONFIGURATION; TANDEM; MECHANISM; SYSTEM;

D O I：

10.1016/j.tet.2019.130857

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review traces the development of the [1,2]- and [1,4]-Wittig rearrangement and their applications in organic synthesis for the past twenty years. The mechanisms are discussed along with detailed analysis of reaction scope and stereochemistry. Applications are reviewed in the context of synthesis of chiral ligands, ring constriction reactions and tandem reactions with the [1,2]-/[1,4]-Wittig rearrangements involved, etc. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页数：12

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