A two-dimensional spin model of Al/Si order in feldspars: visualization of short-range and long-range order

被引:7
作者
Vinograd, VL [1 ]
Putnis, A [1 ]
机构
[1] Univ Munster, Inst Mineral, D-48149 Munster, Germany
关键词
Al; Si ordering; feldspars; cluster variation method; anti-phase domains;
D O I
10.1127/0935-1221/01/0013-0273
中图分类号
P57 [矿物学];
学科分类号
070901 ;
摘要
Ordering schemes analogous to the Al,Si ordering in albite and anorthite are simulated using a two-dimensional spin model. Equilibrium calculations are performed using the square approximation of the cluster variation method. A stochastic algorithm is developed to visualize ordering patterns and domain textures of typical Al,Si configurations with short- and long-range order. At the rather low Al/Si ratio of albite a high degree of short-range order (SRO) is expected as a consequence of strong interaction within first-neighbour Al,Si pairs. At a higher Al/Si ratio of anorthite long-range order (LRO) of anorthite-type appears to be a better alternative to the SRO. The SRO/LRO transition occurs due to the destabilization of anti-phase boundaries between short-range ordered domains. LRO of albite-type is stabilized mainly by the interaction within second-neighbour Al,Si pairs, which is less strong in comparison to the first-neighbor interaction.
引用
收藏
页码:273 / 288
页数:16
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