Kinetics of Allyl Alcohol Epoxidation with Hydrogen Peroxide Catalyzed by a TS-1/Al2O3

被引：1

作者：

Sulimov, A. ^{[1
]}

Ovcharova, A. ^{[1
]}

Ovcharov, A. ^{[1
]}

Sulimova, J. ^{[1
]}

机构：

[1] Nizhnii Novgorod State Tech Univ, Minin St 24, Nizhnii Novgorod 603950, Russia

来源：

CATALYSIS LETTERS | 2019年 / 149卷 / 11期

关键词：

Glycidol; Allyl alcohol; Epoxidation; Hydrogen peroxide; Titanium silicalite; AMORPHOUS SIO2-TIO2 SOLIDS; WETNESS IMPREGNATION; SELECTIVE OXIDATION; GLYCIDOL; TS-1; GLYCEROL; OPTIMIZATION; PARAMETERS; PROPYLENE; CARBONATE;

D O I：

10.1007/s10562-019-02877-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of oxidation of allyl alcohol to glycidol in the presence of extruded titanium silicalite was investigated. Based on the experimental data obtained, a kinetic model of the process was developed and the activation energies of the target and side reactions, the rate constants and the adsorption equilibrium were determined. Testing of the process of allyl alcohol epoxidation was carried out and the adequacy of the proposed kinetic model was evaluated at the bench laboratory installation of continuous action.

引用

页码：3076 / 3086

页数：11

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