Cobalta-Electrocatalyzed C-H Activation in Biomass-Derived Glycerol: Powered by Renewable Wind and Solar Energy

被引：29
作者：
Meyer, Tjark H. [1 ]
Chesnokov, Gleb A. [1 ]
Ackermann, Lutz [1 ]
机构：
[1] Georg August Univ Gottingen, Inst Organ & Biomol Chem, Tammannstr 2, D-37077 Gottingen, Germany
来源：
CHEMSUSCHEM | 2020年 / 13卷 / 04期
关键词：
biomass; C-H activation; cobalt; electrochemistry; renewable energy; sustainability; ORGANIC ELECTROSYNTHESIS; WATER; FUNCTIONALIZATION; HYDROGEN; ELECTROCHEMISTRY; CATALYSIS; ELECTROLYSIS; CHEMISTRY; SOLVENTS; SUNLIGHT;
D O I：
10.1002/cssc.202000057
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Aqueous glycerol was identified as a renewable reaction medium for metalla-electrocatalyzed C-H activation powered by sustainable energy sources. The renewable solvent was employed for cobalt-catalyzed C-H/N-H functionalizations under mild conditions. The cobalta-electrocatalysis manifold occurred with high levels of chemo- and positional selectivity and allowed for electrochemical C-H activations with broad substrate scope. The resource economy of this strategy was considerably substantiated by the direct use of renewable solar and wind energy.
引用
收藏
页码：668 / 671
页数：4
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