Capillary induced twisting of Janus cylinders

被引:3
作者
Oratis, Alexandros T. [1 ]
Farmer, Timothy P. [1 ]
Bird, James C. [1 ]
机构
[1] Boston Univ, Dept Mech Engn, Boston, MA 02215 USA
基金
美国国家科学基金会;
关键词
FLUID INTERFACES; PARTICLES; WETTABILITY; EMULSIONS;
D O I
10.1039/c7sm01288h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
At the appropriate length scales, capillary forces exerted by a liquid in contact with a compliant solid can cause the solid's deformation. Capillary forces are also able to align particles with discrete wettabilities - or Janus particles - at liquid interfaces. Their amphiphilic properties enable Janus particles to orient themselves at liquid interfaces such that both of their surfaces are facing their preferred fluid. However, it is unclear how to spontaneously obtain varying degrees of rotational alignment. Here we extend ideas of elasto-capillarity to modulate rotational alignment by connecting amphiphilic Janus cylinders in an antisymmetric configuration. As the Janus cylinders rotate they cause a twisting deformation of rod. We develop both a mathematical model and a physical macroscale setup to relate the angle of twist to the elastic and interfacial properties, which can be used to tune the extent of alignment of Janus particles at air-water interfaces. We additionally extend our analysis to calculate the twist profile on a compliant element with a distributed capillary torque.
引用
收藏
页码:7556 / 7561
页数:6
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