Iron-catalyzed oxidative coupling of arylboronic acids with benzene derivatives through homolytic aromatic substitution

被引：57

作者：

Uchiyama, Nanase ^{[1
]}

Shirakawa, Eiji ^{[1
]}

Nishikawa, Ryo ^{[1
]}

Hayashi, Tamio ^{[1
]}

机构：

[1] Kyoto Univ, Dept Chem, Grad Sch Sci, Kyoto 6068502, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 42期

关键词：

C-H BOND; DIRECT ARYLATION; MANGANESE(III) ACETATE; HETEROAROMATIC BASES; UNACTIVATED ARENES; ARYL RADICALS; BORONIC ACIDS; (HETERO)ARENES; ALDEHYDES; CLEAVAGE;

D O I：

10.1039/c1cc14694g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fe(OTf)(3)-1,10-phenanthroline catalyzes oxidative coupling of arylboronic acids with benzene derivatives using t-BuOOt-Bu as an oxidant. The reaction proceeds through homolytic aromatic substitution with aryl radicals generated from arylboronic acids and t-BuO center dot.

引用

页码：11671 / 11673

页数：3

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