Electrochemical performance of microarc oxidation films formed on AZ91D alloy in two group electrolytes

被引:0
作者
Wang, LS [1 ]
Cai, QZ [1 ]
Wei, BK [1 ]
Liu, QX [1 ]
机构
[1] Huazhong Univ Sci & Technol, State Key Lab Die & Mould Technol, Wuhan 430074, Peoples R China
关键词
AZ91D alloy; electrolyte; microarc oxidation; electrochemical performance;
D O I
暂无
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The phase composition and electrochemical performances of microarc oxidation(MAO) films prepared on AZ91D alloy by using step-down current method in a phosphate electrolyte (P-film) and silicate electrolyte (Si-film) were studied. The results show that P-film is mainly composed of Mg, MgAl2O4 and MgO, and Si-film is composed Of Mg2SiO4 and MgO. There clearly exists a fluoride enriched zone with the thickness of about 1 - 2 mu m for P-film and 0.7 - 1 mu m for Si-film at the MAO coating/substrate interface. The electrochemical tests show that both P-film and Si-film can enhance the corrosion resistance of AZ91D magnesium alloy significantly. The corrosion failure process of the two films in 5 % (mass fraction) NaCl solution is quite different.
引用
收藏
页码:777 / 783
页数:7
相关论文
共 16 条
  • [1] [Anonymous], 1993, Pat. USA, Patent No. [5 264 113, 5264113]
  • [2] Characterization of oxide films formed on Mg-based WE43 alloy using AC/DC anodization in silicate solutions
    Birss, V
    Xia, S
    Yue, R
    Rateick, RG
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (01) : B1 - B10
  • [3] CAI QZ, 2003, NONOFERROUS ALLOY SP, V3, P33
  • [4] Danny, 2001, CORROS SCI, V43, P1295
  • [5] DUE WB, 2000, HEAT TREATMENT METAL, V1, P1
  • [6] Anodizing of pure magnesium in KOH-aluminate solutions under sparking
    Khaselev, O
    Weiss, D
    Yahalom, J
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (05) : 1757 - 1761
  • [7] Liu Y.H., 2003, PRINCIPLE APPL XRAY
  • [8] Anodic processes in plasma electrolytic oxidation of aluminium in alkaline solutions
    Snizhko, LO
    Yerokhin, AL
    Pilkington, A
    Gurevina, NL
    Misnyankin, DO
    Leyland, A
    Matthews, A
    [J]. ELECTROCHIMICA ACTA, 2004, 49 (13) : 2085 - 2095
  • [9] Electrochemical studies of AC/DC anodized Mg alloy in NaCl solution
    Xia, SJ
    Yue, R
    Rateick, RG
    Birss, VI
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (03) : B179 - B187
  • [10] Xue WB, 1998, J AM CERAM SOC, V81, P1365