Crystalline-crystalline block copolymers of regioregular poly(3-hexylthiophene) and polyethylene by ring-opening metathesis polymerization

被引：125

作者：

Radano, CP

Scherman, OA

Stingelin-Stutzmann, N

Müller, C

Breiby, DW

Smith, P

Janssen, RAJ

Meijer, EW

机构：

[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

[2] ETH Honggerberg, Dept Mat, CH-8093 Zurich, Switzerland

[3] Univ London, Queen Mary, Dept Mat, London E1 4NS, England

[4] Riso Natl Lab, Danish Polymer Ctr, DK-4000 Roskilde, Denmark

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 36期

关键词：

D O I：

10.1021/ja054698y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Block copolymers of regioregular poly(3-hexylthiophene) (P3HT) and polyethylene (PE) were synthesized through the chain transfer of olefin-terminated P3HT in the presence of cyclooctene via ring-opening metathesis polymerization (ROMP). Subsequent hydrogenation of the poly(cyclooctene) block yielded high molecular weight, crystalline-crystalline P3HT-PE block copolymers, which are thermally stable and resistant to solvents under ambient conditions. These copolymers were characterized by 1H NMR, DSC, and WAXS and represent the first materials of a class of crystalline-crystalline semiconducting-insulating block copolymers. Copyright © 2005 American Chemical Society.

引用

页码：12502 / 12503

页数：2

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