Sorption behavior of iminodiacetic acid resin for indium

被引:12
|
作者
Xiong Chunhua [1 ]
Yao Caiping [1 ]
机构
[1] Zhejiang Gongshang Univ, Dept Appl Chem, Hangzhou 310035, Peoples R China
关键词
iminodiacetic acid resin; indium(III); sorption; activation energy; enthalpy change;
D O I
10.1016/S1001-0521(08)60106-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In(III) was quantitatively adsorbed by iminodiacetic acid resin (IDAAR) in the medium of pH = 4.52. The statically saturated sorption capacity of IDAAR is 235.5 mg-g(-1). 1.0 mol-L(-1) HCl can be used as an eluant. The elution efficiency is 97.9%. The resin can be regenerated and reused without apparent decrease of sorption capacity. The sorption rate constant is k(298) = 1.94 x 10(-5) s(-1). The apparent sorption activation energy of IDAAR for In(III) is 20.1 kJ(.)mol(-1). The sorption behavior of IDAAR for In(III) obeys the Freundlich isotherm. The enthalpy change is Delta H = 17.2 kJ(.)mol(-1).
引用
收藏
页码:153 / 157
页数:5
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