Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids

被引：52

作者：

Kuninobu, Yoichiro ^{[1
]}

Ohta, Kazuhiro ^{[1
]}

Takai, Kazuhiko ^{[1
]}

机构：

[1] Okayama Univ, Div Chem & Biochem, Grad Sch Nat Sci & Technol, Kita Ku, Okayama 7008530, Japan

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 38期

关键词：

COUPLING REACTIONS; ACTIVATION; COMPLEXES; INSERTION; ARYL; ALKYLATION; ANNULATION; ALKENES; VINYL;

D O I：

10.1039/c1cc12359a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have succeeded in the allylation of aromatic and olefinic C-H bonds of benzoic and acrylic acids using a rhenium catalyst,Re-2(CO)(10). In this reaction, isomerization of the introduced allyl group to the 1-propenyl group did not occur.

引用

页码：10791 / 10793

页数：3

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