Rhenium-catalyzed allylation of C-H bonds of benzoic and acrylic acids

被引:51
|
作者
Kuninobu, Yoichiro [1 ]
Ohta, Kazuhiro [1 ]
Takai, Kazuhiko [1 ]
机构
[1] Okayama Univ, Div Chem & Biochem, Grad Sch Nat Sci & Technol, Kita Ku, Okayama 7008530, Japan
关键词
COUPLING REACTIONS; ACTIVATION; COMPLEXES; INSERTION; ARYL; ALKYLATION; ANNULATION; ALKENES; VINYL;
D O I
10.1039/c1cc12359a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have succeeded in the allylation of aromatic and olefinic C-H bonds of benzoic and acrylic acids using a rhenium catalyst,Re-2(CO)(10). In this reaction, isomerization of the introduced allyl group to the 1-propenyl group did not occur.
引用
收藏
页码:10791 / 10793
页数:3
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