Copper(II)-catalyzed aerobic oxidation of primary alcohols to aldehydes in ionic liquid [bmpy]PF6

被引：157
作者：
Jiang, N [1 ]
Ragauskas, AJ [1 ]
机构：
[1] Georgia Inst Technol, Dept Chem, Atlanta, GA 30322 USA
来源：
ORGANIC LETTERS | 2005年 / 7卷 / 17期
关键词：
D O I：
10.1021/ol051293+
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] A room-temperature aerobic oxidation of primary alcohols to aldehydes catalyzed by the three-component system acetamido-TEMPO/Cu(ClO4)(2)/DMAP in the ionic liquid [bmpy]PF6 has been developed, and the catalysts can be recycled and reused for five runs without any significant loss of catalytic activity.
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页码：3689 / 3692
页数：4
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