Preparation of 2,3-epoxycycloalkanones from bicyclo [n.1.0]alkan-1-ols

被引：15

作者：

Barnier, JP ^{[1
]}

Morisson, V ^{[1
]}

Blanco, L ^{[1
]}

机构：

[1] CNRS, Inst Chim Mol Orsay, Lab Carbocycles, F-91405 Orsay, France

来源：

SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 03期

关键词：

D O I：

10.1081/SCC-100000523

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper- or iron-catalyzed oxidative rearrangement of bicyclo[n.1.0]alkan-1-ols yields 3-hydroperoxycycloalkanones and/or bicyclic peroxyhemiketals, which are transformed into 2,3-epoxy-cycloalkanones by treatment with a base.

引用

页码：349 / 357

页数：9

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