A Stimulus-Responsive Zinc-Iodine Battery with Smart Overcharge Self-Protection Function

被引：157

作者：

Wang Faxing ^{[1
,2
]}

Tseng Jochi ^{[3
]}

Liu Zaichun ^{[4
]}

Zhang Panpan ^{[1
,2
]}

Wang Gang ^{[1
,2
]}

Chen Guangbo ^{[1
,2
]}

Wu Weixing ^{[5
]}

Yu Minghao ^{[1
,2
]}

Wu Yuping ^{[4
]}

Feng Xinliang ^{[1
,2
]}

机构：

[1] Tech Univ Dresden, Ctr Advancing Elect Dresden Cfaed, Mommsenstr 4, D-01069 Dresden, Germany

[2] Tech Univ Dresden, Dept Chem & Food Chem, Mommsenstr 4, D-01069 Dresden, Germany

[3] Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany

[4] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Sch Energy Sci & Engn, Nanjing 211816, Peoples R China

[5] Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

ADVANCED MATERIALS | 2020年 / 32卷 / 16期

基金：

欧洲研究理事会;

关键词：

battery overchange; battery self-protection; metal-I-2; batteries; stimulus-responsive batteries; Zn anodes; STORAGE; OXIDE;

D O I：

10.1002/adma.202000287

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc-iodine aqueous batteries (ZIABs) are highly attractive for grid-scale energy storage due to their high theoretical capacities, environmental friendliness, and intrinsic non-flammability. However, because of the close redox potential of Zn stripping/platting and hydrogen evolution, slight overcharge of ZIABs would induce drastic side reactions, serious safety concerns, and battery failure. A novel type of stimulus-responsive zinc-iodine aqueous battery (SR-ZIAB) with fast overcharge self-protection ability is demonstrated by employing a smart pH-responsive electrolyte. Operando spectroelectrochemical characterizations reveal that the battery failure mechanism of ZIABs during overcharge arises from the increase of electrolyte pH induced by hydrogen evolution as well as the consequent irreversible formation of insulating ZnO at anode and soluble Zn(IO3)(2) at cathode. Under overcharge conditions, the designed SR-ZIABs can be rapidly switched off with capacity degrading to 6% of the initial capacity, thereby avoiding continuous battery damage. Importantly, SR-ZIABs can be switched on with nearly 100% of capacity recovery by re-adjusting the electrolyte pH. This work will inspire the development of aqueous Zn batteries with smart self-protection ability in the overcharge state.

引用

页数：7

共 48 条

[21] Reversible aqueous zinc/manganese oxide energy storage from conversion reactions [J].

Pan, Huilin ;

Shao, Yuyan ;

Yan, Pengfei ;

Cheng, Yingwen ;

Han, Kee Sung ;

Nie, Zimin ;

Wang, Chongmin ;

Yang, Jihui ;

Li, Xiaolin ;

Bhattacharya, Priyanka ;

Mueller, Karl T. ;

Liu, Jun .

NATURE ENERGY, 2016, 1

[22] Light-assisted delithiation of lithium iron phosphate nanocrystals towards photo-rechargeable lithium ion batteries [J].

Paolella, Andrea ;

Faure, Cyril ;

Bertoni, Giovanni ;

Marras, Sergio ;

Guerfi, Abdelbast ;

Darwiche, Ali ;

Hovington, Pierre ;

Commarieu, Basile ;

Wang, Zhuoran ;

Prato, Mirko ;

Colombo, Massimo ;

Monaco, Simone ;

Zhu, Wen ;

Feng, Zimin ;

Vijh, Ashok ;

George, Chandramohan ;

Demopoulos, George P. ;

Armand, Michel ;

Zaghib, Karim .

NATURE COMMUNICATIONS, 2017, 8

[23] Trimethylphosphine-Assisted Surface Fingerprinting of Metal Oxide Nanoparticle by 31P Solid-State NMR: A Zinc Oxide Case Study [J].

Peng, Yung-Kang ;

Ye, Lin ;

Qu, Jin ;

Zhang, Li ;

Fu, Yingyi ;

Teixeira, Ivo F. ;

McPherson, Ian James ;

He, Heyong ;

Tsang, Shik Chi Edman .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (07) :2225-2234

[24] Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation [J].

Qiu, Huayu ;

Du, Xiaofan ;

Zhao, Jingwen ;

Wang, Yantao ;

Ju, Jiangwei ;

Chen, Zheng ;

Hu, Zhenglin ;

Yan, Dongpeng ;

Zhou, Xinhong ;

Cui, Guanglei .

NATURE COMMUNICATIONS, 2019, 10 (1)

[25] Na2V6O16•3H2O Barnesite Nanorod: An Open Door to Display a Stable and High Energy for Aqueous Rechargeable Zn-Ion Batteries as Cathodes [J].

Soundharrajan, Vaiyapuri ;

Sambandam, Balaji ;

Kim, Sungjin ;

Alfaruqi, Muhammad H. ;

Putro, Dimas Yunianto ;

Jo, Jeonggeun ;

Kim, Seokhun ;

Mathew, Vinod ;

Sun, Yang-Kook ;

Kim, Jaekook .

NANO LETTERS, 2018, 18 (04) :2402-2410

[26]

Sun H, 2017, NAT CHEM, V9, P817, DOI [10.1038/nchem.2730, 10.1038/NCHEM.2730]

[27] Self-Healable Electrically Conducting Wires for Wearable Microelectronics [J].

Sun, Hao ;

You, Xiao ;

Jiang, Yishu ;

Guan, Guozhen ;

Fang, Xin ;

Deng, Jue ;

Chen, Peining ;

Luo, Yongfeng ;

Peng, Huisheng .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (36) :9526-9531

[28] A Stretchable Graphitic Carbon/Si Anode Enabled by Conformal Coating of a Self-Healing Elastic Polymer [J].

Sun, Yongming ;

Lopez, Jeffrey ;

Lee, Hyun-Wook ;

Liu, Nian ;

Zheng, Guangyuan ;

Wu, Chun-Lan ;

Sun, Jie ;

Liu, Wei ;

Chung, Jong Won ;

Bao, Zhenan ;

Cui, Yi .

ADVANCED MATERIALS, 2016, 28 (12) :2455-2461

[29]

Thompson S., 2000, United States Patent, Patent No. [US6159631A, 6159631]

[30]

Wang C, 2013, NAT CHEM, V5, P1042, DOI [10.1038/NCHEM.1802, 10.1038/nchem.1802]

← 1 2 3 4 5 →