A Stimulus-Responsive Zinc-Iodine Battery with Smart Overcharge Self-Protection Function

被引：150

作者：

Wang Faxing ^{[1
,2
]}

Tseng Jochi ^{[3
]}

Liu Zaichun ^{[4
]}

Zhang Panpan ^{[1
,2
]}

Wang Gang ^{[1
,2
]}

Chen Guangbo ^{[1
,2
]}

Wu Weixing ^{[5
]}

Yu Minghao ^{[1
,2
]}

Wu Yuping ^{[4
]}

Feng Xinliang ^{[1
,2
]}

机构：

[1] Tech Univ Dresden, Ctr Advancing Elect Dresden Cfaed, Mommsenstr 4, D-01069 Dresden, Germany

[2] Tech Univ Dresden, Dept Chem & Food Chem, Mommsenstr 4, D-01069 Dresden, Germany

[3] Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany

[4] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Sch Energy Sci & Engn, Nanjing 211816, Peoples R China

[5] Sun Yat Sen Univ, Sch Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

ADVANCED MATERIALS | 2020年 / 32卷 / 16期

基金：

欧洲研究理事会;

关键词：

battery overchange; battery self-protection; metal-I-2; batteries; stimulus-responsive batteries; Zn anodes; STORAGE; OXIDE;

D O I：

10.1002/adma.202000287

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Zinc-iodine aqueous batteries (ZIABs) are highly attractive for grid-scale energy storage due to their high theoretical capacities, environmental friendliness, and intrinsic non-flammability. However, because of the close redox potential of Zn stripping/platting and hydrogen evolution, slight overcharge of ZIABs would induce drastic side reactions, serious safety concerns, and battery failure. A novel type of stimulus-responsive zinc-iodine aqueous battery (SR-ZIAB) with fast overcharge self-protection ability is demonstrated by employing a smart pH-responsive electrolyte. Operando spectroelectrochemical characterizations reveal that the battery failure mechanism of ZIABs during overcharge arises from the increase of electrolyte pH induced by hydrogen evolution as well as the consequent irreversible formation of insulating ZnO at anode and soluble Zn(IO3)(2) at cathode. Under overcharge conditions, the designed SR-ZIABs can be rapidly switched off with capacity degrading to 6% of the initial capacity, thereby avoiding continuous battery damage. Importantly, SR-ZIABs can be switched on with nearly 100% of capacity recovery by re-adjusting the electrolyte pH. This work will inspire the development of aqueous Zn batteries with smart self-protection ability in the overcharge state.

引用

页数：7

共 48 条

[1] Minimal architecture zinc-bromine battery for low cost electrochemical energy storage [J].

Biswas, Shaurjo ;

Senju, Aoi ;

Mohr, Robert ;

Hodson, Thomas ;

Karthikeyan, Nivetha ;

Knehr, Kevin W. ;

Hsieh, Andrew G. ;

Yang, Xiaofang ;

Koel, Bruce E. ;

Steingart, Daniel A. .

ENERGY & ENVIRONMENTAL SCIENCE, 2017, 10 (01) :114-120

[2] An Electrolytic Zn-MnO2 Battery for High-Voltage and Scalable Energy Storage [J].

Chao, Dongliang ;

Zhou, Wanhai ;

Ye, Chao ;

Zhang, Qinghua ;

Chen, Yungui ;

Gu, Lin ;

Davey, Kenneth ;

Qiao, Shi-Zhang .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (23) :7823-7828

[3]

Chen Z, 2016, NAT ENERGY, V1, DOI [10.1038/NENERGY.2015.9, 10.1038/nenergy.2015.9]

[4] Detection and localization of surgically resectable cancers with a multi-analyte blood test [J].

Cohen, Joshua D. ;

Li, Lu ;

Wang, Yuxuan ;

Thoburn, Christopher ;

Afsari, Bahman ;

Danilova, Ludmila ;

Douville, Christopher ;

Javed, Ammar A. ;

Wong, Fay ;

Mattox, Austin ;

Hruban, Ralph. H. ;

Wolfgang, Christopher L. ;

Goggins, Michael G. ;

Dal Molin, Marco ;

Wang, Tian-Li ;

Roden, Richard ;

Klein, Alison P. ;

Ptak, Janine ;

Dobbyn, Lisa ;

Schaefer, Joy ;

Silliman, Natalie ;

Popoli, Maria ;

Vogelstein, Joshua T. ;

Browne, James D. ;

Schoen, Robert E. ;

Brand, Randall E. ;

Tie, Jeanne ;

Gibbs, Peter ;

Wong, Hui-Li ;

Mansfield, Aaron S. ;

Jen, Jin ;

Hanash, Samir M. ;

Falconi, Massimo ;

Allen, Peter J. ;

Zhou, Shibin ;

Bettegowda, Chetan ;

Diaz, Luis A., Jr. ;

Tomasetti, Cristian ;

Kinzler, Kenneth W. ;

Vogelstein, Bert ;

Lennon, Anne Marie ;

Papadopoulos, Nickolas .

SCIENCE, 2018, 359 (6378) :926-+

[5] Tactile UV- and Solar-Light Multi-Sensing Rechargeable Batteries with Smart Self-Conditioned Charge and Discharge [J].

Fang, Zhengsong ;

Zhang, You ;

Hu, Xuanhe ;

Fu, Xinlong ;

Dai, Liming ;

Yu, Dingshan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (27) :9248-9253

[6] Making waves in a photoactive polymer film [J].

Gelebart, Anne Helene ;

Mulder, Dirk Jan ;

Varga, Michael ;

Konya, Andrew ;

Vantomme, Ghislaine ;

Meijer, E. W. ;

Selinger, Robin L. B. ;

Broer, Dirk J. .

NATURE, 2017, 546 (7660) :632-+

[7] Layered VS2 Nanosheet-Based Aqueous Zn Ion Battery Cathode [J].

He, Pan ;

Yan, Mengyu ;

Zhang, Guobin ;

Sun, Ruimin ;

Chen, Lineng ;

An, Qinyou ;

Mai, Liqiang .

ADVANCED ENERGY MATERIALS, 2017, 7 (11)

[8] Highly Durable Na2V6O16•1.63H2O Nanowire Cathode for Aqueous Zinc-Ion Battery [J].

Hu, Ping ;

Zhu, Ting ;

Wang, Xuanpeng ;

Wei, Xiujuan ;

Yan, Mengyu ;

Li, Jiantao ;

Luo, Wen ;

Yang, Wei ;

Zhang, Wencui ;

Zhou, Liang ;

Zhou, Zhiqiang ;

Mai, Liqiang .

NANO LETTERS, 2018, 18 (03) :1758-1763

[9] A self-healable and highly stretchable supercapacitor based on a dual crosslinked polyelectrolyte [J].

Huang, Yan ;

Zhong, Ming ;

Huang, Yang ;

Zhu, Minshen ;

Pei, Zengxia ;

Wang, Zifeng ;

Xue, Qi ;

Xie, Xuming ;

Zhi, Chunyi .

NATURE COMMUNICATIONS, 2015, 6

[10] High-capacity zinc-ion storage in an open-tunnel oxide for aqueous and nonaqueous Zn-ion batteries [J].

Kaveevivitchai, Watchareeya ;

Manthiram, Arumugam .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (48) :18737-18741

← 1 2 3 4 5 →