Reactive Cobalt-Oxo Complexes of Tetrapyrrolic Macrocycles and N-based Ligand in Oxidative Transformation Reactions

被引：35

作者：

Ali, Atif ^{[1
]}

Akram, Waseem ^{[1
]}

Liu, Hai-Yang ^{[1
]}

机构：

[1] South China Univ Technol, Dept Chem, Key Lab Fuel Cell Technol Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China

来源：

MOLECULES | 2019年 / 24卷 / 01期

基金：

中国国家自然科学基金;

关键词：

cobalt-oxo complex; tetrapyrrolic macrocycles; N-based ligand; identification; ELECTROCATALYTIC WATER OXIDATION; OXYGEN EVOLUTION; HIGHLY EFFICIENT; CARBONYL-COMPOUNDS; HYDROGEN-PEROXIDE; AEROBIC OXIDATION; CRYSTAL-STRUCTURE; REACTION PATHWAYS; CATALYST; OXIDE;

D O I：

10.3390/molecules24010078

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

High-valent cobalt-oxo complexes are reactive transient intermediates in a number of oxidative transformation processes e.g., water oxidation and oxygen atom transfer reactions. Studies of cobalt-oxo complexes are very important for understanding the mechanism of the oxygen evolution center in natural photosynthesis, and helpful to replicate enzyme catalysis in artificial systems. This review summarizes the development of identification of high-valent cobalt-oxo species of tetrapyrrolic macrocycles and N-based ligands in oxidation of organic substrates, water oxidation reaction and in the preparation of cobalt-oxo complexes.

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页数：17

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