Selective transformation of biomass-derived 5-hydroxymethylfurfural into 2,5-dihydroxymethylfuran via catalytic transfer hydrogenation over magnetic zirconium hydroxides

被引:40
作者
Hu, Lei [1 ]
Yang, Mei [1 ]
Xu, Ning [1 ]
Xu, Jiaxing [1 ]
Zhou, Shouyong [1 ]
Chu, Xiaozhong [1 ]
Zhao, Yijiang [1 ]
机构
[1] Huaiyin Normal Univ, Jiangsu Key Lab Biomass Based Energy & Enzyme Tec, Sch Chem & Chem Engn, Jiangsu Collaborat Innovat Ctr Reg Modern Agr & E, Huaian 223300, Peoples R China
基金
中国国家自然科学基金;
关键词
5-Hydroxymethylfurfural; 2,5-Dihydroxymethylfuran; 2-Butanol; Catalytic Transfer Hydrogenation; Magnetic Zirconium Hydroxides; MEERWEIN-PONNDORF-VERLEY; HIGHLY EFFICIENT CATALYST; SOLID ACID CATALYSTS; ONE-POT PRODUCTION; GAMMA-VALEROLACTONE; ETHYL LEVULINATE; BUILDING-BLOCK; ELECTROCATALYTIC HYDROGENATION; FE3O4-AT-C NANOPARTICLES; FURANIC COMPOUNDS;
D O I
10.1007/s11814-017-0238-3
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An economical and effective approach for the selective transformation of biomass-derived 5-hydroxymethylfurfural (HMF) into 2,5-dihydroxymethylfuran (DHMF) was developed by catalytic transfer hydrogenation over various magnetic zirconium hydroxides (MZHs). As expected, MZH with a moderate Zr/Fe molar ratio of 2 displayed the highest catalytic activity, resulting in 98.4% HMF conversion and 89.6% DHMF yield at 150 A degrees C for 5 h in the presence of 2-butanol that simultaneously acted as the hydrogen donor and reaction solvent, which was ascribed to its appropriate specific surface area, pore size and acid-base content. Moreover, a plausible reaction mechanism for the catalytic transfer hydrogenation of HMF into DHMF over MHZ(Zr/Fe=2) was also proposed, in which the basic hydroxyl groups with the aid of acidic zirconium metal centers were considered to be responsible for the pivotal hydride transfer via a six-membered ring structure.
引用
收藏
页码:99 / 109
页数:11
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