Oxidation of 5-hydroxymethylfurfural to maleic anhydride with molecular oxygen

被引：159

作者：

Du, Zhongtian ^{[1
]}

Ma, Jiping ^{[1
,2
]}

Wang, Feng ^{[1
]}

Liu, Junxia ^{[1
,2
]}

Xu, Jie ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China

来源：

GREEN CHEMISTRY | 2011年 / 13卷 / 03期

基金：

中国国家自然科学基金;

关键词：

CATALYZED AEROBIC OXIDATION; ALPHA-HYDROXY KETONES; 2,5-FURANDICARBOXYLIC ACID; VANADYL SULFATE; CHEMICALS; BIOMASS; FRUCTOSE; EFFICIENT; ALCOHOLS; CLEAVAGE;

D O I：

10.1039/c0gc00837k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5-Hydroxymethylfurfural (HMF) was converted to maleic anhydride in 52% yield via selective oxidation with molecular oxygen using VO(acac)(2) as catalyst in liquid phase.

引用

页码：554 / 557

页数：4

共 44 条

[21] Gold-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural in Water at Ambient Temperature [J].

Gorbanev, Yury Y. ;

Klitgaard, Soren K. ;

Woodley, John M. ;

Christensen, Claus H. ;

Riisager, Anders .

CHEMSUSCHEM, 2009, 2 (07) :672-675

[22]

Guliants VV, 2005, SPR-CATAL, V18, P1

[23] One-pot, two-step, practical catalytic synthesis of 2,5-diformylfuran from fructose [J].

Halliday, GA ;

Young, RJ ;

Grushin, VV .

ORGANIC LETTERS, 2003, 5 (11) :2003-2005

[24] Efficient conversion of glucose into 5-hydroxymethylfurfural catalyzed by a common Lewis acid SnCl4 in an ionic liquid [J].

Hu, Suqin ;

Zhang, Zhaofu ;

Song, Jinliang ;

Zhou, Yinxi ;

Han, Buxing .

GREEN CHEMISTRY, 2009, 11 (11) :1746-1749

[25] Production of platform chemicals and synthesis gas from biomass [J].

Kamm, B. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (27) :5056-5058

[26] Aerobic oxidation of α-hydroxycarbonyls catalysed by trichlorooxyvanadium:: efficient synthesis of α-dicarbonyl compounds [J].

Kirihara, M ;

Ochiai, Y ;

Takizawa, S ;

Takahata, H ;

Nemoto, H .

CHEMICAL COMMUNICATIONS, 1999, (15) :1387-1388

[27] Highly chemoselective, oxyvanadium-catalysed cleavage of α-hydroxy ketones [J].

Kirihara, M ;

Takizawa, S ;

Momose, T .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1998, (01) :7-8

[28] Tetranuclear vanadium complex, (VO)4(hpic)4: a recyclable catalyst for oxidation of benzyl alcohols with molecular oxygen [J].

Kodama, Shintaro ;

Ueta, Yukihiro ;

Yoshida, Jun ;

Nomoto, Akihiro ;

Yano, Shigenobu ;

Ueshima, Michio ;

Ogawa, Akiya .

DALTON TRANSACTIONS, 2009, (44) :9708-9711

[29] A new approach for the production of 2,5-furandicarboxylic acid by in situ oxidation of 5-hydroxymethylfurfural starting from fructose [J].

Kröger, M ;

Prüsse, U ;

Vorlop, KD .

TOPICS IN CATALYSIS, 2000, 13 (03) :237-242

[30] Production of Oxidized Derivatives of 5-Hydroxymethylfurfural (HMF) [J].

Lilga, Michael A. ;

Hallen, Richard T. ;

Gray, Michel .

TOPICS IN CATALYSIS, 2010, 53 (15-18) :1264-1269

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