Facile routes to patterned surface neutralization layers for block copolymer lithography

被引:151
作者
Bang, Joona [2 ]
Bae, Joonwon [3 ]
Lowenhielm, Peter [1 ]
Spiessberger, Christian [1 ]
Given-Beck, Susan A. [1 ]
Russell, Thomas P. [3 ]
Hawker, Craig J. [1 ]
机构
[1] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA
[2] Univ Seoul, Dept Biol & Chem Engn, Seoul 136713, South Korea
[3] Univ Massachusetts, Dept Polymer Sci & Engn, Amherst, MA 01003 USA
关键词
D O I
10.1002/adma.200701866
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new crosslinking system based on azide-functionalized random copolymers has been defined for the preparation of substrates with controllable surface interactions. The azido group is used for both thermal- and photo-crosslinking, which is found to be very efficient. Furthermore, the use of UV irradiation for crosslinking enables the preparation of patterned surfaces by conventional photolithographic techniques, combining the "bottom-up" self-assembly of block copolymer strategies with traditional "top-down" photolithographic methods.
引用
收藏
页码:4552 / +
页数:7
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