Efficient and Selective Oxidation of 5-Hydroxymethylfurfural into 2, 5-Diformylfuran Catalyzed by Magnetic Vanadium-Based Catalysts with Air as Oxidant

被引：15

作者：

Lai, Jinhua ^{[1
]}

Zhou, Shuolin ^{[1
]}

Cheng, Feng ^{[1
]}

Guo, Dongwen ^{[1
]}

Liu, Xianxiang ^{[1
,2
]}

Xu, Qiong ^{[1
]}

Yin, Dulin ^{[1
]}

机构：

[1] Hunan Normal Univ, Natl & Local Joint Engn Lab New Petrochem Mat & F, Key Lab Assembly & Applicat Organ Funct Mol Hunan, Changsha 410081, Peoples R China

[2] Chinese Acad Sci, CAS Key Lab Renewable Energy, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China

来源：

CATALYSIS LETTERS | 2020年 / 150卷 / 05期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

5-Hydroxymethylfurfural; 2; 5-Diformylfuran; Selective oxidation; Magnetic catalyst; Biomass transformation; AEROBIC OXIDATION; VPO CATALYSTS; H-BETA; 2,5-DIFORMYLFURAN; DERIVATIVES; CONVERSION; CARBON;

D O I：

10.1007/s10562-019-03041-w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, a new kind of magnetic vanadium-based catalyst was successfully prepared and employed to produce 2, 5-diformylfuran (DFF) in the liquid phase through selective oxidation of biomass-derived 5-hydroxymethylfurfur (HMF) with air as oxidant. It was found that magnetic Fe3O4 nanoparticles supported NH4 center dot V3O8 showed excellent catalytic performance with the achievement of 95.5% HMF conversion along with 82.9% selectivity to DFF under optimal reaction conditions. More importantly, the catalyst could be readily separated from the reaction mixture by a permanent magnet, and recycled several times without the loss of its catalytic activity. Graphic The NH4 center dot V3O8/Fe3O4 catalyst showed high activity for selective oxidation of 5-hydroxymethylfurfural into 2, 5-diformylfuran.

引用

页码：1301 / 1308

页数：8

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