Enhanced reactive H2S adsorption using carbon nanofibers supported with Cu/CuxO nanoparticles

被引：41

作者：

Bajaj, Bharat ^{[1
]}

Joh, Han-Ik ^{[2
]}

Jo, Seong Mu ^{[1
,3
]}

Park, Ji Hye ^{[4
]}

Yi, Kwang Bok ^{[5
]}

Lee, Sungho ^{[1
,3
]}

机构：

[1] Korea Inst Sci & Technol, Carbon Composite Mat Res Ctr, 92 Chudong Ro, Wanju Gun 55324, Jeollabuk Do, South Korea

[2] Konkuk Univ, Dept Energy Engn, 120 Neungdong Ro, Seoul 05029, South Korea

[3] Korea Univ Sci & Technol, Dept Nano Mat Engn, 217 Gajeong Ro, Daejeon 34113, South Korea

[4] Chungnam Natl Univ, Grad Sch Energy Sci & Technol, 99 Daehak Ro, Daejeon 34134, South Korea

[5] Chungnam Natl Univ, Dept Chem Engn Educ, 99 Daehak Ro, Daejeon 34134, South Korea

来源：

APPLIED SURFACE SCIENCE | 2018年 / 429卷

关键词：

Electrospinning; Carbon nanofiber; Hydrogen sulfide; Adsorption; Nanoparticles; ACTIVATED CARBON; HYDROGEN-SULFIDE; COPPER; DESULFURIZATION; REGENERATION; TEMPERATURE; PERFORMANCE; REMOVAL; FIBERS; OXIDES;

D O I：

10.1016/j.apsusc.2017.06.280

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Activated carbon nanofibers (ACNFs) modified with Cu/CuxO nanoparticles were prepared from the carbonization of electrospun polyacrylonitrile/copper precursor nanofibers, followed by a mild-activation process. Dynamic breakthrough test for hydrogen sulfide adsorption were conducted at 300 degrees C, and more than 15 times enhancement in the breakthrough time is observed for ACNF with the nanoparticles (938 min) compared to pure ACNF (62 min). The dramatic enhancement is attributed to the presence of well dispersed Cu/CuxO nanoparticles, which exposed on the surface during the mild activation. In addition, ACNFs as supporting layers plays an important role in preventing aggregation of nanoparticles. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：253 / 257

页数：5

共 20 条

[1] Characterization of Mn and Cu oxides as regenerable sorbents for hot coal gas desulfurization [J].

Alonso, L ;

Palacios, JM ;

García, E ;

Moliner, R .

FUEL PROCESSING TECHNOLOGY, 2000, 62 (01) :31-44

[2] Effect of Carbon Nanofibers Supported With Metal Oxide Nanoparticles on H2S Adsorbent Properties [J].

Bajaj, Bharat ;

SujeongKim ;

Park, Moon Kyu ;

Yi, Kwang-Bok ;

Hwang, JunYeon ;

Han-IkJoh ;

Jo, Seong-Mu ;

Lee, Sungho .

ADVANCED SCIENCE LETTERS, 2014, 20 (5-6) :1224-1227

[3] High temperature hydrogen sulfide adsorption on activated carbon II. Effects of gas temperature, gas pressure and sorbent regeneration [J].

Cal, MP ;

Strickler, BW ;

Lizzio, AA ;

Gangwal, SK .

CARBON, 2000, 38 (13) :1767-1774

[4] Enhanced reactive adsorption of H2S on Cu-BTC/S- and N-doped GO composites [J].

Ebrahim, Amani M. ;

Jagiello, Jacek ;

Bandosz, Teresa J. .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (15) :8194-8204

[5] A high-performance adsorbent for hydrogen sulfide removal [J].

Elyassi, Bahman ;

Al Wahedi, Yasser ;

Rajabbeigi, Nafiseh ;

Kumar, Prashant ;

Jeong, Jong Seok ;

Zhang, Xueyi ;

Kumar, Parveen ;

Balasubramanian, Veerappan V. ;

Katsiotis, Marios S. ;

Mkhoyan, K. Andre ;

Boukos, Nikos ;

Al Hashimi, Saleh ;

Tsapatsis, Michael .

MICROPOROUS AND MESOPOROUS MATERIALS, 2014, 190 :152-155

[6] Adsorption of hydrogen sulfide onto activated carbon fibers: Effect of pore structure and surface chemistry [J].

Feng, WG ;

Kwon, S ;

Borguet, E ;

Vidic, R .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (24) :9744-9749

[7] Effect of moisture on H2S adsorption by copper impregnated activated carbon [J].

Huang, Chen-Chia ;

Chen, Chien-Hung ;

Chu, Shu-Min .

JOURNAL OF HAZARDOUS MATERIALS, 2006, 136 (03) :866-873

[8] Preparation of flexible zinc oxide/carbon nanofiber webs for mid-temperature desulfurization [J].

Kim, Soojung ;

Bajaj, Bharat ;

Byun, Chang Ki ;

Kwon, Soon-Jin ;

Joh, Han-Ik ;

Yi, Kwang Bok ;

Lee, Sungho .

APPLIED SURFACE SCIENCE, 2014, 320 :218-224

[9] The sorption of hydrogen sulfide from hot syngas by metal oxides over supports [J].

Ko, TH ;

Chu, H ;

Chaung, LK .

CHEMOSPHERE, 2005, 58 (04) :467-474

[10] Morphologies and surface properties of cellulose-based activated carbon nanoplates [J].

Lee, Seulbee ;

Lee, Min Eui ;

Song, Min Yeong ;

Cho, Se Youn ;

Yun, Young Soo ;

Jin, Hyoung-Joon .

CARBON LETTERS, 2016, 20 (01) :32-38

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