The Synthesis, Spectroscopic, Fluorescence, and Thermal Properties of a 1,10-phenanthroline Containing Derivative of Phenoxycyclotriphosphazene and its Ru(II) Complex

被引：6
作者：
Kecin, Ibrahim [1 ]
Elmali, Fikriye Tuncel [1 ]
Demirhan, Nebahat [1 ]
机构：
[1] Yildiz Tech Univ, Fac Arts & Sci, Dept Chem, TR-34210 Istanbul, Turkey
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 01期
关键词：
1; 10-phenanthroline; cyclotriphosphazene; Ru complex; BENZYLCYANIDE SPACER; POLYPHOSPHAZENES; RUTHENIUM; CHEMISTRY; LIGAND;
D O I：
10.1080/15533174.2010.522666
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new phenoxycyclotriphosphazene derivative ligand, 2-chloro -2-salicylideneimino-1,10-phenanthrolino-4,4,6,6-bis[spiro(2',2''-dioksi-1',1''-bifenil)]cyclotriphosp- hazane (CS-CP), has been synthesized from the reaction of 2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxybiphenyl)] cyclotriphosphazane and 5-salicylideneimino-1,10-phenanthroline and Ru(II) complex of this ligand has been prepared. The newly synthesized compounds have been verified by FTIR,1H NMR, 31P NMR, UV-vis., mass, and fluorescence spectra, together with elemental and thermal analysis.
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页码：1 / 7
页数：7
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