Secondary current distribution in a curvilinear Hull cell

被引:6
作者
Lee, JW [1 ]
Chapman, TW [1 ]
机构
[1] Univ Wisconsin, Dept Chem Engn, Madison, WI 53706 USA
关键词
D O I
10.1149/1.1838760
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The secondary current distribution is calculated for current flow between planar electrodes placed on two radii of an annular section, forming a cell with concentric cylindrical walls. The curved walls are insulators, and there are no variations in the axial direction of the cylindrical coordinate system. The anode is taken to be reversible, and the cathodic reaction-kinetics function is Linear. The current distribution is found as a function of geometric ratios and a dimensionless polarization parameter. It is suggested that a cell of this geometry may be used to measure quantitative throwing power as well as to observe qualitative properties of plating-bath solutions.
引用
收藏
页码:3042 / 3046
页数:5
相关论文
共 9 条
[1]   RAPID COMPUTATION OF CURRENT DISTRIBUTION BY ORTHOGONAL COLLOCATION [J].
CABAN, R ;
CHAPMAN, TW .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1976, 123 (07) :1036-1041
[2]  
HARING HE, 1923, T ELECTROCHEM SOC, V44, P313
[3]  
HULL RO, 1939, AM ELECTROPLAT SOC, V27, P52
[4]   SECONDARY CURRENT DISTRIBUTION IN A HULL CELL - BOUNDARY ELEMENT AND FINITE-ELEMENT SIMULATION AND EXPERIMENTAL-VERIFICATION [J].
MATLOSZ, M ;
CRETON, C ;
CLERC, C ;
LANDOLT, D .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (12) :3015-3021
[5]  
NEWMAN J, 1991, ELECTROCHEMICAL SYST, P340
[6]  
TERAKADO R, 1979, MET FINISH, P17
[8]   COMPUTING POLARIZATION CURVES FOR THE ROTATING-DISK ELECTRODE BY ORTHOGONAL COLLOCATION [J].
YEN, SC ;
CHAPMAN, TW .
CHEMICAL ENGINEERING COMMUNICATIONS, 1985, 38 (3-6) :159-180
[9]  
YEN SC, 1994, PLAT SURF FINISH, V81, P56