Free radical reaction promoted by ionic liquid: a route for metal-free oxidation depolymerization of lignin model compound and lignin

被引：64
|
作者：
Yang, Yingying [1 ]
Fan, Honglei [1 ]
Song, Jinliang [1 ]
Meng, Qinglei [1 ]
Zhou, Huacong [1 ]
Wu, Lingqiao [1 ]
Yang, Guanying [1 ]
Han, Buxing [1 ]
机构：
[1] Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 19期
基金：
中国国家自然科学基金;
关键词：
C-O BOND; BIOMASS FRACTIONATION; CATALYZED CLEAVAGE; AEROBIC OXIDATION; DARK OXIDATION; STEP SYNTHESIS; CARBON; HYDRODEOXYGENATION; HYDROGENOLYSIS; PHENOLS;
D O I：
10.1039/c4cc10394g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ionic liquid 1-benzyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide ([BnMIm][NTf2]) can promote the generation of the (OOH)-O-center dot free radical and thereby efficiently transformed the beta-O-4 lignin model compound 2-phenoxyacetophenone into benzoic acid and phenol using O-2 as the oxidant. Furthermore, the IL-based metal-free catalytic system can also depolymerize other lignin model compounds and organosolv lignin effectively.
引用
收藏
页码：4028 / 4031
页数：4
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