Electrical conductivity of Cs2CuCl4 crystals

被引：2

作者：

Sorokin, N. I. ^{[1
]}

机构：

[1] Russian Acad Sci, AV Shubnikov Crystallog Inst, Moscow 119333, Russia

来源：

CRYSTALLOGRAPHY REPORTS | 2016年 / 61卷 / 03期

关键词：

CSCL-CUCL2-H2O; PRESSURE; HALIDES; SYSTEM;

D O I：

10.1134/S1063774516020255

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The electrical conductivity of Cs2CuCl4 single crystals, synthesized by crystallization from aqueous solutions in the CsCl-CuCl2-H2O system, has been investigated. The temperature dependence of the electrical conductivity of crystals in a temperature range of 338-584 K exhibits no anomalies. The electrical transfer activation enthalpy is Delta H (sigma) = 0.72 +/- 0.05 eV and the conductivity is sigma = 3 x 10(-4) S/cm at 584 K. The most likely carriers in Cs2CuCl4 are Cs+ cations, which transfer electric charge according to the vacancy mechanism.

引用

页码：466 / 468

页数：3

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