Supramolecular daisy chains

被引：2
|
作者：
Ashton, PR
Baxter, I
Cantrill, SJ
Fyfe, MCT
Glink, PT
Stoddart, JF
White, AJP
Williams, DJ
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, Chem Crystallog Lab, London SW7 2AY, England
[2] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 09期
关键词：
crown compounds; host-guest chemistry; noncovalent interactions; self-assembly; supramolecular chemistry;
D O I：
10.1002/(SICI)1521-3773(19980518)37:9<1294::AID-ANIE1294>3.0.CO;2-F
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Our childhoods may be recalled when a self-complementary cation, endowed with both a dibenzo[24]crown-8 macroring and a secondary dialkylammonium sidearm, self-assembles to form a two-component supramolecular architecture that is reminiscent of a daisy chain (depicted schematically on the right). This daisy-chain-like super-architecture is stabilized by a combination of [N+-H ··· O] hydrogen bonds and aryl-aryl stacking interactions.
引用
收藏
页码：1294 / 1297
页数：4
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