Catalytic hydrogen production at cobalt centres

被引：274

作者：

Losse, Sebastian ^{[1
,2
]}

Vos, Johannes G. ^{[3
]}

Rau, Sven ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Lehrstuhl Anorgan Allgemeine Chem, Egerlandstr 1, D-91058 Erlangen, Germany

[2] Univ Jena, Inst Anorgan & Analyt Chem, D-07743 Jena, Germany

[3] Dublin City Univ, Solar Energy Convers SRC, Sch Chem Sci, Dublin 9, Ireland

来源：

COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 21-22期

基金：

爱尔兰科学基金会;

关键词：

Photocatalysis; Ruthenium; Cobalt; Hydrogen; VISIBLE-LIGHT IRRADIATION; CARBON-DIOXIDE; HOMOGENEOUS CATALYSIS; ELECTRON-TRANSFER; PHOTO-REDUCTION; ELECTROCATALYTIC REDUCTION; FUNCTIONAL MODELS; METAL-COMPLEXES; WATER; EVOLUTION;

D O I：

10.1016/j.ccr.2010.06.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The catalytic properties of a wide range of cobalt complexes with respect to proton reduction are discussed. Electrocatalytic as well as photocatalytic systems are addressed and to allow comparison between the different systems reported considerable attention is paid to the reaction conditions used. For the photocatalytic proton reduction a range of ruthenium, iridium and rhenium complexes are discussed as potential photosensitizers. The photocatalytic systems are discussed in detail and issues such as the nature of the sacrificial agent and the solvents used. Both intermolecular and intramolecular photocatalysis are considered. The results obtained are considered with respect to the need to the development of sustainable energy sources. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：2492 / 2504

页数：13

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