Novel nanofiber-based triple-layer proton exchange membranes for fuel cell applications

被引:56
作者
Hasani-Sadrabadi, Mohammad Mahdi [2 ,3 ]
Shabani, Iman [1 ,2 ]
Soleimani, Masoud [4 ]
Moaddel, Homayoun [5 ]
机构
[1] Stem Cell Technol Res Ctr, Nanotechnol & Tissue Engn Dept, Tehran, Iran
[2] Amirkabir Univ Technol, Dept Polymer Engn & Color Technol, Tehran, Iran
[3] Lausanne EPFL, Swiss Fed Inst Technol, Inst Bioengn, CH-1015 Lausanne, Switzerland
[4] Tarbiat Modares Univ, Fac Med Sci, Dept Hematol, Tehran, Iran
[5] Hydrogen & Fuel Cell Inc, Arcadia, CA USA
关键词
Nanofiber; Electrospinning; Triple-layer membrane; Polyelectrolyte; Fuel cell; COMPOSITE MEMBRANES; NAFION; MONTMORILLONITE; PERFORMANCE;
D O I
10.1016/j.jpowsour.2011.01.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
New types of triple-layer membranes were fabricated using multi-step impregnation of Nation in electrospun webs based on bead-free nanofibers of sulfonated poly(ether sulfone) (SPES). The results showed that the fabricated nanofiber-filled membrane owing to its reduced methanol permeability as well as sufficient proton conductivity and membrane selectivity can be used as a promising proton exchange membrane for direct methanol fuel cell (DMFC) applications. The single cell DMFC performance results revealed that the SPES nanofiber-based triple-layer membranes have higher electrochemical performance than commercial Nation membranes. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:4599 / 4603
页数:5
相关论文
共 19 条
[1]   Silicon oxide Nafion composite membranes for proton-exchange membrane fuel cell operation at 80-140° C [J].
Adjemian, KT ;
Lee, SJ ;
Srinivasan, S ;
Benziger, J ;
Bocarsly, AB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (03) :A256-A261
[2]   Overview of hybrid membranes for direct-methanol fuel-cell applications [J].
Ahmad, H. ;
Kamarudin, S. K. ;
Hasran, U. A. ;
Daud, W. R. W. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (05) :2160-2175
[3]  
BABAEIJANDAGHI F, 2010, TISSUE ENG PART A, V16, P3236
[4]   Electrospinning and solution properties of Nafion and poly(acrylic acid) [J].
Chen, Hong ;
Snyder, Joshua D. ;
Elabd, Yossef A. .
MACROMOLECULES, 2008, 41 (01) :128-135
[5]   Nanofiber network ion-exchange membranes [J].
Choi, Jonghyun ;
Lee, Kyung Min ;
Wycisk, Ryszard ;
Pintauro, Peter N. ;
Mather, Patrick T. .
MACROMOLECULES, 2008, 41 (13) :4569-4572
[6]   Nafion-impregnated electrospun polyvinylidene fluoride composite membranes for direct methanol fuel cells [J].
Choi, S. W. ;
Fu, Y. -Z. ;
Ahn, Y. R. ;
Jo, S. M. ;
Manthiram, A. .
JOURNAL OF POWER SOURCES, 2008, 180 (01) :167-171
[7]   Polymer electrolyte membranes for the direct methanol fuel cell: A review [J].
Deluca, Nicholas W. ;
Elabd, Yossef A. .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2006, 44 (16) :2201-2225
[8]   Acid-base blend membranes based on 2-amino-benzimidazole and sulfonated poly(ether ether ketone) for direct methanol fuel cells [J].
Fu, Yongzhu ;
Manthiram, Arumugam ;
Guiver, Michael D. .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (05) :905-910
[9]   Novel nanocomposite proton exchange membranes based on Nafion® and AMPS-modified montmorillonite for fuel cell applications [J].
Hasani-Sadrabadi, Mohammad Mahdi ;
Dashtimoghadam, Erfan ;
Majedi, Fatemeh S. ;
Kabiri, Kourosh ;
Solati-Hashjin, Mehran ;
Moaddel, Homayoun .
JOURNAL OF MEMBRANE SCIENCE, 2010, 365 (1-2) :286-293
[10]   Novel high-performance nanohybrid polyelectrolyte membranes based on bio-functionalized montmorillonite for fuel cell applications [J].
Hasani-Sadrabadi, Mohammad Mahdi ;
Dashtimoghadam, Erfan ;
Majedi, Fatemeh S. ;
Kabiri, Kourosh ;
Mokarram, Nassir ;
Solati-Hashjin, Mehran ;
Moaddel, Homayoun .
CHEMICAL COMMUNICATIONS, 2010, 46 (35) :6500-6502