The internal and external factor on coal ash slag viscosity at high temperatures, Part 1: Effect of cooling rate on slag viscosity, measured continuously

被引:58
作者
Kong, Lingxue [1 ]
Bai, Jin [1 ]
Li, Wen [1 ]
Wen, Xiaodong [1 ]
Li, Xiaoming [2 ]
Bai, Zongqing [1 ]
Guo, Zhenxing [1 ]
Li, Huaizhu [1 ]
机构
[1] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
[2] Harbin Engn Univ, Coll Power & Energy Inst, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
Entrained flow gasification; Continuous measurement; Cooling rate; Slag viscosity; T-CV; AUSTRALIAN BITUMINOUS COALS; FLOW PROPERTIES; PREDICTIONS; FUSIBILITY; BEHAVIOR;
D O I
10.1016/j.fuel.2015.02.055
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Entrained flow gasification employs a high temperature, high pressure slagging gasifier, in which slag viscosity plays a key role in determining operating conditions. The effect of cooling rate on viscosity properties were investigated by high temperature rotational viscometer. Viscosities of two slag, which exhibited glassy and crystalline slag behavior, were determined under continuous measurement conditions. The results showed that viscosities of two slag both decreased with increasing cooling rate. When the temperature was above the liquidus temperature (T-Liquidus), the difference between slag viscosities was small. However, it showed a large difference below T-Liquidus, and a more obviously effect was observed on crystalline slag. Above T-Liquidus, slag viscosity only depended on the bulk composition of slag which was little affected by cooling rate, resulting in the small difference between viscosities measured at different cooling rates. Below T-Liquidus, slag viscosity was closely related to the amount of solid phase that was greatly affected by cooling rate. For glassy slag, mullite was not crystalized in slag during cooling, and slag viscosity depended on the compositions of slag. However, for crystalline slag, anorthite was crystalized in slag, and its amount significantly decreased with increasing cooling rate, leading to the large difference between viscosities measured at different cooling rates. Meanwhile, temperature of critical viscosity (T-CV) decreased with increasing cooling rate, and a good linear relationship existed between T-CV and cooling rate. Furthermore, T-CV measured under equilibrium conditions was able to be predicted by the linear regression formula of the "continuous measurement'' experiments data. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:968 / 975
页数:8
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